The essence of the methane fermentation course is the phase nature of changes taking place during the process. The biodegradation degree of sewage sludge is determined by the effectiveness of the hydrolysis phase. Excess sludge, in the form of a fl occulent suspension of microorganisms, subjected to the methane fermentation process show limited susceptibility to the biodegradation. Excess sludge is characterized by a signifi cant content of volatile suspended solids equal about 65 ÷ 75%. Promising technological solution in terms of increasing the effi ciency of fermentation process is the application of thermal modifi cation of sludge with the use of dry ice. As a result of excess sludge disintegration by dry ice, denaturation of microbial cells with a mechanical support occurs. The crystallization process takes place and microorganisms of excess sludge undergo the so-called "thermal shock". The aim of the study was to determine the effect of dry ice disintegration on the course of the methane fermentation process of the modifi ed excess sludge. In the case of dry ice modifi cation reagent in a granular form with a grain diameter of 0.6 mm was used. Dry ice was mixed with excess sludge in a volume ratio of 0.15/1, 0.25/1, 0.35/1, 0.45/1, 0.55/1, 0.65/1, 0.75/1, respectively. The methane fermentation process lasting for 8 and 28 days, respectively, was carried out in mesophilic conditions at 37°C. In the fi rst series untreated sludge was used, and for the second and third series the following treatment parameters were applied: the dose of dry ice in a volume ratio to excess sludge equal 0.55/1, pretreatment time 12 hours. The increase of the excess sludge disintegration degree, as well as the increase of the digestion degree and biogas yield, was a confi rmation of the supporting operation of the applied modifi cation. The mixture of reactant and excess sludge in a volume ratio of 0.55/1 was considered the most favorable combination. In relation to not prepared sludge for the selected most favorable conditions of excess sludge modifi cation, about 2.7 and 3-fold increase of TOC and SCOD values and a 2.8-fold increase in VFAs concentration were obtained respectively.In relation to the effects of the methane fermentation of non-prepared sludge, for modifi ed sludge, about 33 percentage increase of the sludge digestion degree and about 31percentage increase of the biogas yield was noticed.