2021
DOI: 10.1063/5.0069623
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Hyper-Rayleigh scattering of adenine, thymine, and cytosine in neat water

Abstract: The first hyperpolarizability of the DNA bases Thymine and Cytosine were determined by Hyper Rayleigh Scattering in neat water despite their low solubility. Due to the low intensity levels collected, count statistics was performed instead of the standard dilution procedure. The first hyperpolarizability were found to be 𝛽 = (2.99 ± 0.44) × 10 esu for Thymine and 𝛽 = (3.35 ± 0.21) × 10 esu for Cytosine. Due to its weak solubility, only an upper limit 𝛽 < (1.82 ± 0.10) × 10 esu could be set for Adenine. The f… Show more

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