2023
DOI: 10.1016/j.cej.2022.140218
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Hyperbranched nanocellulose enabling rapid boron removal from aqueous environment

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Cited by 14 publications
(4 citation statements)
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“…In addition, this analysis highlights the crucial role of NMDG groups in facilitating boron adsorption by means of mono - and bis -chelate complexes and leading to enhanced boron adsorption of polymeric resin. The surface modification and hyperbranching of cellulose by functional groups such as NMDG groups are expected to improve the boron adsorption properties of cellulose materials, because of the structural/conformational flexibility associated with both pyranose rings and pendent NMDG side chains. , …”
Section: Resultsmentioning
confidence: 99%
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“…In addition, this analysis highlights the crucial role of NMDG groups in facilitating boron adsorption by means of mono - and bis -chelate complexes and leading to enhanced boron adsorption of polymeric resin. The surface modification and hyperbranching of cellulose by functional groups such as NMDG groups are expected to improve the boron adsorption properties of cellulose materials, because of the structural/conformational flexibility associated with both pyranose rings and pendent NMDG side chains. , …”
Section: Resultsmentioning
confidence: 99%
“…2D 1 H− 13 C correlation experiments provide enhanced resolution, enabling the 1 H peaks corresponding to the different moieties to be identified and analyzed. In the 2D 13 C− 1 H HETCOR spectrum of boron-adsorbed resin (Figure 15,16 To compare the relative boron-adsorption capacity of cellulose and Amberlite IRA743, the peak integrals of monoand bis-chelate complexes obtained from the deconvolution of 1D 11 B NMR spectra of the Amberlite IRA743 were analyzed and compared. A detailed explanation of the estimation of the boron-adsorption capacity is given in the Supporting Information (SI, Section 15, as well as Figure S14 and Table S5).…”
Section: ■ Results and Discussionmentioning
confidence: 99%
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“…The strategic integration of nanofillers and the interfacial polymerization process can effectively overcome the shortcomings of PA-TFC and PA-thin-film nanocomposite (TFN) membranes. The applications of nanofillers such as covalent organic frameworks (COFs), metal–organic frameworks (MOFs), layered double hydroxides (LDHs), carbon-based nanoparticles, and graphene oxides have been extensively researched for enhanced separation performance. ,, Traditionally, the incorporation of nanofillers can be done either in the aqueous or organic phase for interfacial polymerization, predeposition in the sublayer, or as coating postpolymerization . Other strategies like molecular plug, steric hindrance, surface tailoring, and surface charge introduction have also been reported to enhance chlorine-resistance in membranes. …”
Section: Introductionmentioning
confidence: 99%