2010
DOI: 10.1103/physreva.82.052514
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Hyperfine, rotational, and vibrational structure of thea3Σu+state ofRb

Abstract: We have performed high-resolution two-photon dark-state spectroscopy of an ultracold gas of 87 Rb2 molecules in the a 3 Σ + u state at a magnetic field of about 1000 G. The vibrational ladder as well as the hyperfine and low-lying rotational structure is mapped out. Energy shifts in the spectrum are observed due to singlet-triplet mixing at binding energies as deep as a few hundred GHz×h. This information together with data from other sources is used to optimize the potentials of the a 3 Σ + u and X 1 Σ + g st… Show more

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Cited by 132 publications
(168 citation statements)
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References 44 publications
(69 reference statements)
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“…Here we use an extension that allows for a second-order spin-orbit interaction [29] and a hyperfine-contact interaction that depends on the internuclear separation R. The effect of this second correction was recently studied for Rb 2 [30]. Finally, we have…”
Section: B Feshbach Spectroscopymentioning
confidence: 99%
“…Here we use an extension that allows for a second-order spin-orbit interaction [29] and a hyperfine-contact interaction that depends on the internuclear separation R. The effect of this second correction was recently studied for Rb 2 [30]. Finally, we have…”
Section: B Feshbach Spectroscopymentioning
confidence: 99%
“…Instead, the most significant coupling between the atomic and molecular states is provided by the dependence of the hyperfine coupling constant of the alkali-metal atom on the internuclear distance R [19]. Such R dependences exist in alkali-metal dimers [31], but in that case they merely produce small shifts in bound-state energies and resonance positions, rather than driving new resonances. If the closed-shell atom has nonzero nuclear spin, it can also couple to the unpaired electron spin.…”
Section: Introductionmentioning
confidence: 99%
“…6(a) is about k max 2 = 5.3×10 −21 cm 3 s −1 , which is not far from the value of 1.25×10 −20 cm 3 s −1 obtained for 87 Rb on the potentials of Ref. [16]. Figure 9 shows a contour plot similar to function of magnetic field, as shown for 87 Rb in Fig.…”
Section: B Inelastic Collisions Of Rf-dressed 87 Rbmentioning
confidence: 57%
“…The potential curves for the singlet and triplet states are taken from Ref. [16] for Rb 2 and from Ref. [17] for K 2 .…”
Section: Methodsmentioning
confidence: 99%
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