Abstract:The title complex, [ZnBr2(C7H6N4)]n, was formed under hydrothermal conditions using the ligand 4-(3-pyridyl)-4H-1,2,4-triazole (L). The unique ZnII ion is coordinated by one triazole N atom, one pyridine N atom and two Br atoms in a slightly distorted tetrahedral coordination environment. Symmetry-related ZnII ions are connected by bridging L ligands into chains parallel to [001] in which the Zn⋯Zn separation is 8.643 (7) Å. In the crystal structure, weak intermolecular C—H⋯Br hydrogen bonds link the chain… Show more
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