catena-Poly[[trimethyltin(IV)]-μ-2-(3-thienyl)acetato]

Abstract

The title compound, [Sn(CH3)3(C6H5O2S)]n, forms an infinite chain structure parallel to [100]. There are two mol­ecules of the complex in the asymmetric unit. The geometry of the Sn atoms in both mol­ecules is distorted trigonal-bipyramidal. The S and C atoms of the thio­phene rings in both mol­ecules are disordered over two sites with site-occupancy factors 0.799 (9)/0.201 (9) and 0.618 (7)/0.382 (7), respectively.

Crystal structure ofcatena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ2O:O′]

“…For related structures see: Tahir et al (1997a,b); Tariq et al (2013); Yang et al (2009); Wen et al (2009); Danish et al (2015) Table 1 Selected bond lengths (Å ).…”

“…The crystal structures of catena-Poly [[trimethyltin(IV)]-µ-2-(2-chlorophenyl) acetato] (Wen et al, 2009), catena-[bis- (Yang et al, 2009), catena- ((µ2-2-(3-benzoylphenyl)propanoato-)-trimethyl-tin(iv)) (Tahir et al, 1997a), {2-[(2,3-Dimethylphenyl)amino] benzoato-O:O′}trimethyltin(IV) (Tahir et al, 1997b) have been published which are related to the title compound due to coordination around the tin.…”