cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ²N,N′]bis(dimethyl sulfoxide-κO)cadmium

Abstract

Key indicators: single-crystal X-ray study; T = 150 K; mean (C-C) = 0.006 Å; disorder in main residue; R factor = 0.045; wR factor = 0.102; data-to-parameter ratio = 14.9.The complete molecule of the title compound, [Cd(C 10 H 9 N 4 O 2 S) 2 (C 2 H 6 OS) 2 ], is completed by the application of a twofold rotation axis. The Cd II atom is six coordinated by two bidentate sulfadiazinate anions and two dimethylsulfoxide molecules. The resulting N 4 O 2 donor set displays a distorted trigonal-prismatic coordination geometry. The S atom and methyl groups of dimethylsulfoxide are disordered over two sets of sites, with site occupancies of 0.715 (4) and 0.285 (4). The crystal structure features intermolecular N-HÁ Á ÁN and N-HÁ Á ÁO hydrogen bonds that lead to the formation of layers in the ab plane. Related literature ExperimentalCrystal data [Cd(C 10

Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)cadmium dimethylformamide disolvate

“…The bond distance C18-N14 of 1.359 (3)Å is comparable with the value of 1.366 (5)Å (Hossain, 2011). The torsion angle C15-S11-N11-C11 of 53.5 (2)° is less than the value of 66.1 (3)° and the dihedral angle between the aromatic rings of the anion of 76.60 (8)° is also smaller than the value of 88.65 (12)° in the sulfadiazinate anion (Hossain, 2011) because the large 4,4′-dimethyl-2,2′-bipyridine (dmbpy) ligand is attached to the Cd ion in the complex. Due to the presence of the larger dmbpy molecule the torsion and dihedral angles are reduced from the latter one where small dmf molecules are attached with the metal centre.…”

“…For the comparison of the N-H bond distance of the terminal amine group and the C-S-N-C torsion angle, see: Heren et al (2006); Hossain & Amoroso (2007); Hossain (2011). For the hydrogen bonds of sulfadiazinate anions, see: Paşaog lu et al (2008).…”

“…For the hydrogen bonds of sulfadiazinate anions, see: Paşaog lu et al (2008). For the comparison of the dihedral angle between the aromatic rings of the anion, see: Hossain & Amoroso (2007); Hossain (2011). For the comparison of Cd-N bond distances, see: Kalateh et al (2010); Hossain (2011).…”

Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ2N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate

“…The bond angles around the S atom correspond to a distorted tetrahedral geometry. The bond distance C-N (Terminal amino group) of 1.369 (4) and 1.375 (4)Å and the torsion angle C-S-N-C of 66.2 (3)° and -54.7 (3)° are comparable to those observed in the related structures (Heren et al, 2006;Hossain & Amoroso, 2007;Hossain, 2011).…”

“…The later one is comparable with the value of 71.10 (14)° (Hossain & Amoroso, 2007) in the sulfadiazinate anion. The packing of (I) ( (Table 2) and exists among sdz anions, coordinated and solvated water molecules (Hossain, 2011).…”