2007
DOI: 10.1107/s0108270107040504
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cis-Bis(dimethyl sulfide)dinitratoplatinum(II) at 295 and 150 K

Abstract: The title compound, [Pt(NO(3))(2)(C(2)H(6)S)(2)], crystallizes in the P2(1)/n space group (Z' = 2), with pseudo-square-planar coordination geometry. The complex forms dimers with pseudosymmetry C(i) arranged in columns along the b-axis direction, with Pt...Pt distances of 6.3056 (3) and 4.2382 (2) A (at 150 K). Each column is surrounded by six other columns in a honeycomb rod-like packing. The coordination mode of the nitrate ligands is monodentate, with Pt-O-N angles ranging from approximately 117 to approxim… Show more

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