cis-Dibromobis(1,10-phenanthroline)manganese(II)

Abstract

In the title complex, [MnBr2(C24H16N4)], there is a weak C—H⋯Br intermolecular interaction in the crystal structure, giving rise to molecular chains along the a axis.

{2‐[1‐(2,6‐Diisopropylphenylimino)ethyl]pyridyl}palladium Dibromide Polymorphs Originating from Different Br···π and C–H···Br Contacts

“…molecules, [26] including the differentiation of polymorphs [27] as well as related cis-(dibromo)metal [28] and other (multibromo)metal complexes. [29,30] The range of the CH···Br contacts observed in 1 matches the range observed and discussed for the packing in the compound [Ph 2 S=N=SPh 2 ] 2 [Pd 2 Br 6 ].…”

Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate

“…For background to Mn-and phenanthroline-containing complexes, see: Rü ttinger & Dismukes (1997); Wang et al (1996); Wall et al (1999); Naing et al (1995). For related structures, see: Shen & Yuan (2004); Pan & Xu (2005); Su et al (2005); Pan et al (2006); Shen et al (2007); Xuan et al (2007); Zhao et al (2007). 152 restraints H-atom parameters constrained Á max = 0.34 e Å À3 Á min = À0.33 e Å À3 Table 1 Selected geometric parameters (Å , ).…”

“…In addition, metal-phenanthroline complexes and their derivatives have attracted much attention during recent decades because of their peculiar features (Wang et al, 1996;Wall et al, 1999;Naing et al, 1995). A number of Mn (II) complexes have been synthesized and structures determined (Shen & Yuan, 2004;Pan & Xu, 2005;Su et al, 2005;Pan et al, 2006;Shen et al, 2007;Xuan et al, 2007;Zhao et al, 2007). The title complex, (I), was recently obtained from the reaction of manganese nitrate, sodium 2-hydroxybenzoate and dmphen in an ethanol/water mixture, and its crystal structure is reported here.…”