Ammonium (
NH
4
+
) is an undesirable by-product of photocatalytic nitrate (
NO
3
−
) reduction since it is harmful to aquatic life once it converts into ammonia (NH3). This research investigated the removal efficiency of
NO
3
−
and for the first time quantified the relationships of initial nitrate concentrations ([
NO
3
−
]0) and photocatalyst dosages on the remaining ammonium (
NH
4
+
) in synthetic wastewater using photocatalytic reduction process with either nanoparticle titanium dioxide (TiO2) or 1.0%Ag-TiO2 under Ultraviolet A (UVA). The experiments were systematically carried out under various combinations of [
NO
3
−
]0 (10, 25, 50, 80, and 100 mg-N/L) and photocatalyst dosages (0.1, 0.5, 1.0, and 2.0 g). The
NO
3
−
removal efficiency of both photocatalysts was 98.96-99.98%, and the catalytic selectivity products were nitrogen gas (N2), nitrite (
NO
2
−
), and
NH
4
+
. Of the two photocatalysts under comparable experimental conditions, 1.0%Ag-TiO2 provided better
NO
3
−
removal efficiency. For both photocatalysts, the remaining
NH
4
+
was predominantly determined by [
NO
3
−
]0; higher [
NO
3
−
]0 led to higher
NH
4
+
. Multiple linear regression analysis confirmed the dominant role of [
NO
3
−
]0 in the remaining
NH
4
+
. The photocatalyst dosage could play an essential role in limiting
NH
4
+
in the treated wastewater, with large variation in [
NO
3
−
]0 from different sources.