<i>In situ</i> UV-cured composite electrolytes for highly efficient quasi-solid-state lithium ion batteries with wide temperature range applications

Zhou, Pengcheng; Liu, Yuxian; Chen, Jian; Lu, Shouqiang; Li, Huiyang

doi:10.1039/d2se01679f

Cited by 1 publication

(2 citation statements)

References 54 publications

(71 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In general, the cycling performance of the battery increased with the increase in the LALZO fraction in the IPCE. This result is consistent with the conclusions of our previous work . In contrast, the LE-based conventional battery exhibited a poor cycling performance of only 87 cycles with a relatively low Coulombic efficiency of less than 99% during charge and discharge.…”

Section: Resultssupporting

confidence: 93%

“…This result is consistent with the conclusions of our previous work. 46 In contrast, the LE-based conventional battery exhibited a poor cycling performance of only 87 cycles Additionally, a reasonable lifetime of 133 cycles was obtained for the PEO-MSA-LALZO-5-4-based cell at a relatively high discharge rate of 2C at 35 °C, during which a high capacity of 143 mA h g −1 was maintained, and no short circuit was observed even after 1000 cycles. The related curves are shown in Figure 9e.…”

Section: ■ Results and Discussionmentioning

confidence: 91%

See 1 more Smart Citation

Versatile Inorganic/Polymer Composite Electrolyte Added with 2-Methylsuccinic Anhydride via a Solvent-Free Preparation Method for High-Performance All-Solid-State Li-Metal Batteries: High Voltage, Long Cycle Life, and Room-Temperature Operation

Zhou,

Liu,

Chen

et al. 2023

ACS Sustainable Chem. Eng.

Self Cite

View full text Add to dashboard Cite

Solid-state Li-metal batteries (LMBs) with a high room-temperature energy density, long cycle life, and remarkable flexibility and safety are necessary for practical energy-storage applications. In this study, 2-methylsuccinic anhydride was used as a novel additive to fabricate a series of all-solid-state inorganic/polymer composite electrolytes (IPCEs) using a completely solventfree hot-pressing process instead of the conventional solution-casting method. This electrolyte comprises a poly(ethylene oxide) framework that is hybridized with a Li 6.4 Al 0.24 La 3 Zr 2 O 12 inorganic filler. The freestanding IPCE membrane exhibited long-term stability against Li metal and a high ion conductivity of 2.4 × 10 −4 S cm −1 at 25 °C, showing an appreciable transference number of 0.87. All-solid-state LMBs (ASSLBs) fabricated using this IPCE, high-voltage LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) cathode, and lithium foil anode achieved a specific capacity of 163 mA h g −1 at 0.5C and 25 °C. The IPCE inhibited lithium dendrite growth and eventually delivered an excellent battery cycling performance beyond 400 cycles. Moreover, this ASSLB performed well even at 15 °C and showed notable rate performance at 35 °C, at which a capacity of 143 mA h g −1 at 2C was realized for 133 cycles. Remarkably, a pouch cell based on this system exhibited good electrochemical performance, flexibility, and safety. This ASSLB holds great promise for practical energy-storage applications.

show abstract

Section: Resultssupporting

confidence: 93%

Section: ■ Results and Discussionmentioning

confidence: 91%

Versatile Inorganic/Polymer Composite Electrolyte Added with 2-Methylsuccinic Anhydride via a Solvent-Free Preparation Method for High-Performance All-Solid-State Li-Metal Batteries: High Voltage, Long Cycle Life, and Room-Temperature Operation

Zhou,

Liu,

Chen

et al. 2023

ACS Sustainable Chem. Eng.

Self Cite

View full text Add to dashboard Cite

show abstract

In situ UV-cured composite electrolytes for highly efficient quasi-solid-state lithium ion batteries with wide temperature range applications

Abstract: The replacement of flammable electrolytes with non-flammable electrolytes is the ultimate solution for addressing the safety concerns related to lithium-ion batteries. In this context, inorganic/polymer composite electrolytes (IPCEs) offer the...

Cited by 1 publication

References 54 publications

Versatile Inorganic/Polymer Composite Electrolyte Added with 2-Methylsuccinic Anhydride via a Solvent-Free Preparation Method for High-Performance All-Solid-State Li-Metal Batteries: High Voltage, Long Cycle Life, and Room-Temperature Operation

Versatile Inorganic/Polymer Composite Electrolyte Added with 2-Methylsuccinic Anhydride via a Solvent-Free Preparation Method for High-Performance All-Solid-State Li-Metal Batteries: High Voltage, Long Cycle Life, and Room-Temperature Operation

Contact Info

Product

Resources

About