The UV spectra of Galactic and extragalactic sightlines often show O VI absorption lines at a range of redshifts, and from a variety of sources from the Galactic circumgalactic medium to AGN outflows. Inner shell O VI absorption is also observed in X-ray spectra (at λ = 22.03Å), but the column density inferred from the X-ray line was consistently larger than that from the UV line. Here we present a solution to this discrepancy for the z = 0 systems. The O II Kβ line 4 S 0 → ( 3 D)3p 4 P at 562.40 eV (≡22.04Å) is blended with the O VI Kα line in X-ray spectra. We estimate the strength of this O II line in two different ways and show that in most cases the O II line accounts for the entire blended line. The small amount of O VI equivalent width present in some cases has column density entirely consistent with the UV value. This solution to the O VI discrepancy, however, does not apply to the high column density systems like AGN outflows. We discuss other possible causes to explain their UV/X-ray mismatch. The O VI and O II lines will be resolved by gratings on-board the proposed mission Arcus and the concept mission Lynx and would allow detection of weak O VI lines not just at z = 0 but also at higher redshift.