2012
DOI: 10.1107/s1600536812037051
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meso-(1S*,21R*)-25-Methyl-8,11,14-trioxa-22,24,25-triazatetracyclo[19.3.1.02,7.015,20]pentacosa-2,4,6,15(20),16,18-hexaene-23-thione chloroform monosolvate

Abstract: The title compound crystallizes as a chloro­form solvate, C20H23N3O3S·CHCl3, with two crystallographically independent units. The independent units have distinctly different inter­action patterns between the aza­crown macrocycle and the chloro­form solvent mol­ecule. In one of them, the chloro­form mol­ecule forms C—H⋯N and Cl⋯H—C hydrogen bonds with the aza­crown macrocycle (as a proton donor and an acceptor, respectively), whereas in the other, one of the chloro­form mol­ecules is bound to the aza­crown macr… Show more

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Cited by 6 publications
(1 citation statement)
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“…Design, preparation and applications of macroheterocyclic ligands for coordination, supramolecular and medicinal chemistry draw constant attention of investigators during the last several decades (Hiraoka, 1982;Pedersen,1988;Gokel & Murillo, 1996;Bradshaw & Izatt, 1997). Recently we have developed the effective method of synthesis of azacrown ethers including piperidine (Levov et al, 2006); Anh et al, 2008Anh et al, , 2012a, cycloalkanopiperidine (Levov et al 2008); bispidine (Komarova et al;Sokol et al;Hieu et al 2012a;Anh et al 2012c); perhydropyrimidine (Hieu et al, 2011) and perhydrotriazine (Hieu et al, 2009(Hieu et al, , 2012bKhieu et al, 2011) subunits.…”
Section: S1 Commentmentioning
confidence: 99%
“…Design, preparation and applications of macroheterocyclic ligands for coordination, supramolecular and medicinal chemistry draw constant attention of investigators during the last several decades (Hiraoka, 1982;Pedersen,1988;Gokel & Murillo, 1996;Bradshaw & Izatt, 1997). Recently we have developed the effective method of synthesis of azacrown ethers including piperidine (Levov et al, 2006); Anh et al, 2008Anh et al, , 2012a, cycloalkanopiperidine (Levov et al 2008); bispidine (Komarova et al;Sokol et al;Hieu et al 2012a;Anh et al 2012c); perhydropyrimidine (Hieu et al, 2011) and perhydrotriazine (Hieu et al, 2009(Hieu et al, , 2012bKhieu et al, 2011) subunits.…”
Section: S1 Commentmentioning
confidence: 99%