2024
DOI: 10.1021/acs.orglett.4c01233
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meso-Methyl Amination of BODIPYs by Regiospecific Cross Dehydrogenative Coupling via Direct C(sp3)–N(sp3) Bond Formation

Kartik Dutta,
Amey P. Wadawale,
Soumyaditya Mula

Abstract: Herein, we report a direct meso-methyl amination of BODIPY dyes by C(sp 3 )−N(sp 3 ) bond formation using PIDA as an oxidant with a wide range of aliphatic secondary amines. This metal free cross dehydrogenative coupling reaction is regiospecific at the meso-methyl position of BODIPY in the presence of C1, C3, C5, and C7 methyl groups. Detailed nuclear magnetic resonance spectroscopy, high-resolution mass spectrometry, and X-ray crystallographic studies were performed to establish the reaction mechanism and th… Show more

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