3D structure into thin cross-sections and fabricate the structure layer-by-layer. [29] This 3D fabrication route relies mainly on metal powders or polymeric materials that are deposited then cooled, crosslinked, or sintered to create the desired 3D structure. [24,29] While these approaches are very successful for expedited prototyping, the resulting printed 3D structures are typically constrained to nonfunctional materials and have limited functionalities that, based primarily on their geometrical shape. [24] Recent efforts have led to kirigami-inspired fabrication process that uses existing semiconductor fabrication to design 2D patterns of electronic materials that can morph into complex 3D structures by stress-induced buckling. [24,27,28,30] This approach uses lithography to fabricate silicon planar designs with selective sites for bonding. [24,27,28] Once this planar design is transferred onto a strained elastomer substrate, with selective bonding, the relaxation of the substrate will induce strain in unbounded locations of the design, thus converting a 2D planar design into a 3D mesostructure. [24,27,28,[31][32][33] The planar device will bend from its 2D precursor into a diverse library of complex 3D constructs (e.g., baskets, cuboid cages, starbursts, cars, or flowers). [24] While such photolithographic fabrication of 3D structures is scalable for microstructures and suitable for a high-performance electronic materials, this approach is relatively expensive, requires rigorous operating environment and usually involves complex procedures. [34] Other methods, such as laser cutting or mechanical dicing, can be useful for prototyping, but are relatively lowthroughput for large-scale manufacturing. Many disciplines rely on a variety of materials or composites, such as nano materials, smart polymers, alloys, carbonaceous, biomaterials, composites, or temperature-sensitive dyes. [13,14,[35][36][37][38][39][40][41][42][43][44][45][46][47][48] The assimilation of these diverse materials and composites is essential to the widespread use and progression of 3D mesostructures.Here, we introduce a thick-film screen-printing fabrication technique that is high-throughput, low-cost that can produce diverse highly tunable buckled 3D structures (with freestanding segments) composed of different materials, shapes, and sizes. The novelty of the new approach hinges on the formulation and dimensions of the sacrificial layer that can be tailored to control which specific segments of the 2D precursor Current methods to create 3D structures are limited to few materials and designs, are costly, and have low processing throughput. Planar designs (of printed sacrificial, flexible, and guiding layers) fabricated by thick film technique that can reversibly fold between their 2D and 3D forms through compressive buckling and selective bonding is reported in this work. Versatile ink compositions based on a wide variety of materials (e.g., carbonaceous, polymers, and nanomaterials) are used along with screen printing technique for creating ...