<i>N</i>,<i>N</i>′‐bridged binuclear NHC palladium complexes: A combined experimental catalytic and computational study for the Suzuki reaction

Chen, Ming‐Tsz; Hsieh, Bing Yan; Liu, Yi Hung; Wu, Kuo Hui; Lussari, Natália; Braga, Ataualpa Albert Carmo

doi:10.1002/aoc.5870

Cited by 13 publications

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References 88 publications

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“…[27] Chen et al (2020) synthesized a series of 2D CoÀ Zn MOF composites having improved photodegradation activities with increasing cobalt content in the complexes indicating a profound dependence on the metal in enhancing photocatalytic degradation. [28] In this work, the 3D bis[5-(2pyridyl)tetrazolato]diaquacopper(II) (5) coordination polymer [CuP] n , has been synthesized in one-step and structurally characterized by single-crystal X-ray diffraction (Scheme 1). Moreover, a range of new catalysts with tuned band-gap have been fabricated by varying Cu 2 + /Zn 2 + ratios, from zero to absolute concentrations of metals in the ligand backbone {[Cu 1-…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Structure of 3D Bis[5‐(2‐pyridyl)tetrazolato]diquacopper(II) Framework: One‐pot Facile Fabrication of a Series of Catalysts Towards Dye Degradation in Sunlight

et al. 2022

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A copper‐based metal‐organic framework (MOF) Bis[5‐(2‐pyridyl)tetrazolato]diaquacopper(II) [{CuP}n], has been designed and structurally characterized by single‐crystal X‐ray crystallography. The three‐dimensional crystal structure belongs to the monoclinic space group P21/c with Z=4. Further a series of isostructural complexes [{Cu1‐xZnxP}n] (x=1, 0.75, 0.5, 0.25, 0), {P=(5‐(2‐pyridyl)tetrazolato)2.2H2O} have been synthesized via a facile one‐pot microwave irradiated solvothermal method. The optical and photocatalytic properties of the synthesized bimetallic complexes were investigated and compared with those of monometallic complexes. The effects of metal substitutions in the ligand backbone were investigated. A striking variation in the bandgap i. e., from 4.1 eV (x=1) to 2.79 eV (x=0) was observed among the catalysts with a minimum value of 1.93 eV (x=0.25). The optimized catalyst Cu0.75Zn0.25P exhibits the highest degradation activity and reached up to 99 % for RhB (rhodamine B) and 96 % for MB (methylene blue) in 120 min of Sunlight, corresponding to the respective photocatalytic degradation rates of 0.0328 min−1 and 0.0301 min−1. The kinetics of the degradation processes were best statistically described by pseudo‐first‐order. The catalyst was also found to have sufficient stability and recyclability with promising applications in removal of organic dye pollutants.

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Section: Introductionmentioning

confidence: 99%

Synthesis and Structure of 3D Bis[5‐(2‐pyridyl)tetrazolato]diquacopper(II) Framework: One‐pot Facile Fabrication of a Series of Catalysts Towards Dye Degradation in Sunlight

et al. 2022

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N‐Heterocyclic Carbene Palladium(II) Amine Complexes: The Role of Primary Aryl‐ or Alkylamine Binding and Applications in the Buchwald‐Hartwig Amination Reaction

Chen

Hsu

2021

Eur J Inorg Chem

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N-heterocyclic carbene-palladium(II) amine complexes bearing primary aryl-or alkylamines were synthesized. The prepared complexes were characterized by single crystal X-ray diffraction as well as NMR spectroscopy. These complexes exhibited good catalytic activities for the Buchwald-Hartwig amination reaction of aryl chlorides to afford arylated anilines under mild conditions. All reactions were carried out in air and all starting materials were used as supplied without purification. 21 expected coupling products were obtained in moderate to high yields under optimum conditions.

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Bis(imino)acenaphthene N‐Heterocyclic Carbene Palladium Complexes Bearing Tertiary Amines: Structural and Catalytic Studies on the Interaction between Soft Acid and Hard Base

et al. 2022

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The HSAB principle in designing Bis(imino)acenaphthene N‐heterocyclic carbene (NHC) palladium complexes is presented. N‐donor ligands serve as hard bases to enhance the catalytic activities of NHC Pd complexes in Suzuki and Buchwald–Hartwig amination reactions. The Pd complex bearing tertiary amine ligands exhibited higher performance in coupling reactions than those exhibited by other soft base ligands reported in literature. 48 coupling products were generated in moderate‐to‐complete yields in the presence of aryl chlorides as substrates for Suzuki and amination reactions in air under mild conditions.

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N,N′‐bridged binuclear NHC palladium complexes: A combined experimental catalytic and computational study for the Suzuki reaction

Cited by 13 publications

References 88 publications

Synthesis and Structure of 3D Bis[5‐(2‐pyridyl)tetrazolato]diquacopper(II) Framework: One‐pot Facile Fabrication of a Series of Catalysts Towards Dye Degradation in Sunlight

Synthesis and Structure of 3D Bis[5‐(2‐pyridyl)tetrazolato]diquacopper(II) Framework: One‐pot Facile Fabrication of a Series of Catalysts Towards Dye Degradation in Sunlight

N‐Heterocyclic Carbene Palladium(II) Amine Complexes: The Role of Primary Aryl‐ or Alkylamine Binding and Applications in the Buchwald‐Hartwig Amination Reaction

Bis(imino)acenaphthene N‐Heterocyclic Carbene Palladium Complexes Bearing Tertiary Amines: Structural and Catalytic Studies on the Interaction between Soft Acid and Hard Base

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