N-Methylformamide

Mitzel, Thomas M.

doi:10.1002/047084289x.rn01040

Cited by 2 publications

(2 citation statements)

References 31 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Beyond biological applications, NMF and DMF are used on an industrial scale as reactants [ 10 , 11 ] and as excellent solvents for both organic compounds and inorganic electrolytes [ 12 ], because of their chemical bifunctionality and high polarity. They find extensive use in the manufacture of, e.g., pharmaceuticals, pesticides, fibers, adhesives, and coatings.…”

Section: Introductionmentioning

confidence: 99%

Thermodynamic Study of N-Methylformamide and N,N-Dimethyl-Formamide

Růžička,

Štejfa,

Červinka

et al. 2024

Molecules

View full text Add to dashboard Cite

An extensive thermodynamic study of N-methylformamide (CAS RN: 123-39-7) and N,N-dimethylformamide (CAS RN: 68-12-2), is presented in this work. The liquid heat capacities of N-methylformamide were measured by Tian–Calvet calorimetry in the temperature interval (250–300) K. The vapor pressures for N-methylformamide and N,N-dimethylformamide were measured using static method in the temperature range 238 K to 308 K. The ideal-gas thermodynamic properties were calculated using a combination of the density functional theory (DFT) and statistical thermodynamics. A consistent thermodynamic description was developed using the method of simultaneous correlation, where the experimental and selected literature data for vapor pressures, vaporization enthalpies, and liquid phase heat capacities and the calculated ideal-gas heat capacities were treated together to ensure overall thermodynamic consistency of the results. The resulting vapor pressure equation is valid from the triple point to the normal boiling point temperature.

show abstract

Section: Introductionmentioning

confidence: 99%

Thermodynamic Study of N-Methylformamide and N,N-Dimethyl-Formamide

Růžička,

Štejfa,

Červinka

et al. 2024

Molecules

View full text Add to dashboard Cite

show abstract

“…Beyond biological applications, NMF and DMF are used on an industrial scale as reactants [10,11] and as excellent solvents for both organic compounds and inorganic electrolytes [12], because of their chemical bifunctionality and high polarity. They find extensive use in the manufacture of, e.g., pharmaceuticals, pesticides, fibers, adhesives, and coatings.…”

Section: Introductionmentioning

confidence: 99%

Thermodynamic Study of N-methylformamide and N,N-Dimethyl-Formamide

Růžička,

Štejfa,

Červinka

et al. 2024

Preprint

View full text Add to dashboard Cite

An extensive thermodynamic study of N-methylformamide (CAS RN: 123-39-7) and N,N-dimethylformamide (CAS RN: 68-12-2), is presented in this work. The liquid heat capacities of N-methylformamide were measured by Tian–Calvet calorimetry in the temperature interval (250 – 300) K. The vapor pressures for N-methylformamide and N,N-dimethylformamide were measured using static method in the temperature range 238 K to 308 K. The ideal-gas thermo-dynamic properties were calculated using a combination of the density functional theory (DFT) and statistical thermodynamics. A consistent thermodynamic description was developed using the method of simultaneous correlation, where the experimental and selected titerature data for vapor pressures, vaporization enthalpies, and liquid phase heat capacities and calculated ide-al-gas heat capacities are treated together to ensure overall thermodynamic consistency of the results. Resulting vapor pressure equation is valid from the triple point to the normal boiling point temperature.

show abstract

N-Methylformamide

Cited by 2 publications

References 31 publications

Thermodynamic Study of N-Methylformamide and N,N-Dimethyl-Formamide

Thermodynamic Study of N-Methylformamide and N,N-Dimethyl-Formamide

<em></em>Thermodynamic Study of <em>N</em>-methylformamide and <em>N,N</em>-Dimethyl-Formamide

Contact Info

Product

Resources

About