Chem. Commun.
 2024
DOI: 10.1039/d4cc04023f
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syn-1,2-Diaminobenzocyclobutenes from [2+2] cycloaddition of 2-imidazolones with arynes

Haseeb Ur Rehman Shah,
Qi Li,
Christopher R. Jones

Abstract: Formal [2+2] cycloaddition of arynes with 2-imidazolones affords syn-1,2-diaminobenzocyclobutenes. The transformation can also be conducted as a one-pot, three-stage process direct from simple propargyl amines and isocyanates to afford the...

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