To get insight into the mechanism of emergence of unconventional quantum criticality observed in quasicrystal Yb 15 Al 34 Au 51 , the approximant crystal Yb 14 Al 35 Au 51 is analyzed theoretically. By constructing a minimal model for the approximant crystal, the heavy quasiparticle band is shown to emerge near the Fermi level because of strong correlation of 4f electrons at Yb. We find that charge-transfer mode between 4f electron at Yb on the 3rd shell and 3p electron at Al on the 4th shell in Tsai-type cluster is considerably enhanced with almost flat momentum dependence.The mode-coupling theory shows that magnetic as well as valence susceptibility exhibits χ ∼ T −0.5 for zero-field limit and is expressed as a single scaling function of the ratio of temperature to magnetic field T/B over four decades even in the approximant crystal when some condition is satisfied by varying parameters, e.g., by applying pressure. The key origin is clarified to be due to the strong locality of the critical Yb-valence fluctuation and small Brillouin zone reflecting the large unit cell, giving rise to the extremely-small characteristic energy scale. This also gives a natural explanation for the quantum criticality in the quasicrystal corresponding to the infinite limit of the unit-cell size.Recent discovery of unconventional quantum critical phenomena in quasicrystal Yb 15 Al 34 Au 51 has attracted much attention.1, 2) The measured criticality such as magnetic susceptibility χ ∼ T −0.5 , NMR relaxation rate (T 1 T ) −1 ∼ T −0.5 , specific heat C e /T ∼ − log T , and resistivity ρ ∼ T is unconventional and quite similar to those observed in periodic crystals such as heavy-electron metals YbRh 2 Si 2 3) and β-YbAlB 4 , 4,5) which are well explained by quantum critical phenomena of Yb-valence fluctuations.6)The quasicrystal Yb 15 Al 34 Au 51 is constituted of concentric shell structures of Tsai-type cluster shown in Fig. 1. 1, 7) There also exists approximant crystal Yb 14 Al 35 Au 51 .7) The approximant crystal has periodic arrangement of the body-centered cubic (bcc) structure whose unit cell contains shell structures shown in Figs. 1(a)-1(e). Theoretical analysis of the Yb-AlAu cluster taking account of critical Yb-valence fluctuations has provided a natural explanation for robustness of quantum criticality in the quasicrystal measured under pressure and has pointed out a possibility that the same criticality appears even in the approximant crystal when pressure is applied. 8,9) On the other hand, a new theoretical framework for critical Yb-valence fluctuation under magnetic field has been developed recently.10) The theory has succeeded in explaining novel scaling discovered in β-YbAlB 4 where the magnetic susceptibility χ is expressed as a single scaling function of the ratio of temperature to magnetic field T/B over four decades.
5)Surprisingly, recent measurement of magnetic susceptibility in the quasicrystal Yb 15 Al 34 Au 51 has revealed that the same T/B-scaling behavior appears over six decades of T/B.11) This strongly s...