tert-Butylhydroperoxide mediated radical cyanoalkylation/cyanoalkenylation of 2-anilino-1,4-naphthoquinones with vinylarenes/arylalkynes and azobis(alkylcarbonitrile)s

Abstract

We disclosed a TBHP mediated cyanoalkylation/cyanoalkenylation reaction of 2-anilino-1,4-naphthoquinones with vinylarenes/arylalkynes and azobis(alkylcarbonitrile)s in a one-pot three-component fashion via a radical cascade pathway.