trans-(4-Acetylnaphthyl)chloridobis(triphenylphosphine-κP)nickel(II) dichloromethane solvate

Abstract

Key indicators: single-crystal X-ray study; T = 296 K; mean (C-C) = 0.011 Å; R factor = 0.080; wR factor = 0.183; data-to-parameter ratio = 15.0.The title compound, [Ni(C 12 H 9 O)Cl(C 18 H 15 P) 2 ]ÁCH 2 Cl 2 , was synthesized from the reaction between 1-acetyl-4-chloronaphthalene, NiCl 2 Á6H 2 O and triphenylphosphine (PPh 3 ) in ethanol. The compound contains one crystallographically unique nickel ion in a pseudo-square-planar geometry. Related literature