trans-Bis(acetato-O)bis(2-amino-6-methylpyridine-N)copper(II)

Lah, Nina; Golič, L.; Šegedin, Primož; Leban, I.

doi:10.1107/s0108270199004345

Cited by 3 publications

(2 citation statements)

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“…Coordinating nitrogen and oxygen atoms form a square plane geometry around the copper atom, with distances Cu(1)‐O(10 A) 1.9247(13) Å and Cu(1)‐N(21) 2.0197(15) Å. Bond lengths and angles are in good agreement with literature values for other copper square planar complexes ,…”

Section: Resultssupporting

confidence: 84%

“…Bond lengths and angles are in good agreement with literature values for other copper square planar complexes. [12,[23][24][25][26][27] The other oxygen atom of the carboxylate group (O10B) is not bonded with the copper centre (CuÀO10B 2.945(2) Å ). This coordinating mode of pOHBz ligand differs from the reported for 1, where the carboxylate group shows bidentate bonding mode, although with notably dissimilar CuÀO distances (1.971 and 2.520 Å ).…”

Section: Crystal Structure Of [Cu(pohbz) 2 (4-phpy) 2 ] (2)mentioning

confidence: 99%

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Effect of the Pyridine Substituent on the Role of the Phenol Functional Group in [Cu(pOHBz)₂(dPy)₂] Complexes (pOHBz: p‐Hydroxybenzoate, dPy= 4‐Phenylpyridine, 4‐Benzylpyridine, 3‐Phenylpyridine).

et al. 2017

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The crystal structure of three new complexes of stoichiometry [Cu(pOHBz)2(dPy)2] (pOHBz: p‐hydroxybenzoate, dPy= 4‐phenylpyridine, 4‐benzylpyridine, 3‐phenylpyridine) and its comparison with the previously reported [Cu(pOHBz)2(Py)2] (1) indicate that the nature and position of the pyridine substituent determines different roles for the phenol group from the pOHBz ligand and, consequently, the coordination number and geometry of Cu(II) centers. Results herein reported show the versatility of the pOHBz ligand towards the coordination of Cu(II). Different carboxylate bonding modes are also observed: monodentate, bidentate chelating or bidentate bridge. Besides, this governs the different roles of the phenol group of the pOHBz ligand: founding of supramolecular hydrogen‐bond based network or direct bonding to the copper cation, yielding 2D coordination polymers.

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Section: Resultssupporting

confidence: 84%

Section: Crystal Structure Of [Cu(pohbz) 2 (4-phpy) 2 ] (2)mentioning

confidence: 99%

Effect of the Pyridine Substituent on the Role of the Phenol Functional Group in [Cu(pOHBz)₂(dPy)₂] Complexes (pOHBz: p‐Hydroxybenzoate, dPy= 4‐Phenylpyridine, 4‐Benzylpyridine, 3‐Phenylpyridine).

et al. 2017

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Lah

Šegedin

Leban

2002

Structural Chemistry

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Copper(ii) halogenopropionates: low-temperature crystal and molecular structure of bis(2,2-dichloropropionato)-di(methyl-3-pyridylcarbamate)copper(ii) and bis(2-bromopropionato)-di (2-pyridylmethanol)copper(ii)

Moncóľ

Múdra

Lönnecke

et al. 2004

Journal of Coordination Chemistry

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trans-Bis(acetato-O)bis(2-amino-6-methylpyridine-N)copper(II)

Cited by 3 publications

References 4 publications

Effect of the Pyridine Substituent on the Role of the Phenol Functional Group in [Cu(pOHBz)₂(dPy)₂] Complexes (pOHBz: p‐Hydroxybenzoate, dPy= 4‐Phenylpyridine, 4‐Benzylpyridine, 3‐Phenylpyridine).

Effect of the Pyridine Substituent on the Role of the Phenol Functional Group in [Cu(pOHBz)₂(dPy)₂] Complexes (pOHBz: p‐Hydroxybenzoate, dPy= 4‐Phenylpyridine, 4‐Benzylpyridine, 3‐Phenylpyridine).

Untitled

Copper(ii) halogenopropionates: low-temperature crystal and molecular structure of bis(2,2-dichloropropionato)-di(methyl-3-pyridylcarbamate)copper(ii) and bis(2-bromopropionato)-di (2-pyridylmethanol)copper(ii)

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trans-Bis(acetato-O)bis(2-amino-6-methylpyridine-N)copper(II)

Cited by 3 publications

References 4 publications

Effect of the Pyridine Substituent on the Role of the Phenol Functional Group in [Cu(pOHBz)2(dPy)2] Complexes (pOHBz: p‐Hydroxybenzoate, dPy= 4‐Phenylpyridine, 4‐Benzylpyridine, 3‐Phenylpyridine).

Effect of the Pyridine Substituent on the Role of the Phenol Functional Group in [Cu(pOHBz)2(dPy)2] Complexes (pOHBz: p‐Hydroxybenzoate, dPy= 4‐Phenylpyridine, 4‐Benzylpyridine, 3‐Phenylpyridine).

Untitled

Copper(ii) halogenopropionates: low-temperature crystal and molecular structure of bis(2,2-dichloropropionato)-di(methyl-3-pyridylcarbamate)copper(ii) and bis(2-bromopropionato)-di (2-pyridylmethanol)copper(ii)

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Effect of the Pyridine Substituent on the Role of the Phenol Functional Group in [Cu(pOHBz)₂(dPy)₂] Complexes (pOHBz: p‐Hydroxybenzoate, dPy= 4‐Phenylpyridine, 4‐Benzylpyridine, 3‐Phenylpyridine).

Effect of the Pyridine Substituent on the Role of the Phenol Functional Group in [Cu(pOHBz)₂(dPy)₂] Complexes (pOHBz: p‐Hydroxybenzoate, dPy= 4‐Phenylpyridine, 4‐Benzylpyridine, 3‐Phenylpyridine).