<i>trans</i>-Bis(acetonitrile-<i>N</i>)tetraaquanickel(II) dibromide

Assoumatine, Tokouré; Stœckli-Evans, Helen

doi:10.1107/s1600536801005323

Cited by 7 publications

(7 citation statements)

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“…Single Crystal Analysis. Single crystals of ( 39 Diffracted intensities were collected on a Rigaku XtaLAB Synergy diffractometer equipped with a Dualflex source (Cu Kα radiation, λ = 1.54184 Å) and a HyPix detector using ω-scans. Data were collected at 170 K, except for the (12−2−12) 2 [NiBr 2 (H 2 O) 4 ]Br 4 •2H 2 O structure, for which data were gathered at 293 K. The collected data were processed using the CrysAlis program package.…”

Section: Synthesis Of Dimeric Metallosurfactants (12−2−12)[mbr 4 ]mentioning

confidence: 99%

Transition Metal-Based Dimeric Metallosurfactants: From Organic–Inorganic Hybrid Structures and Low-Dimensional Magnets to Metallomicelles

Rubčić,

Herak,

Zagorec

et al. 2024

Inorg. Chem.

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Section: Synthesis Of Dimeric Metallosurfactants (12−2−12)[mbr 4 ]mentioning

confidence: 99%

Transition Metal-Based Dimeric Metallosurfactants: From Organic–Inorganic Hybrid Structures and Low-Dimensional Magnets to Metallomicelles

Rubčić,

Herak,

Zagorec

et al. 2024

Inorg. Chem.

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“…The coordination chemistry of the title compound m-bis L1 (I), an N 2 S 6 thiapyrazinophane, has also been studied and shown to form a binuclear complex with CuBr 2 and a twodimensional coordination polymer with CuI (Assoumatine & Stoeckli-Evans, 2020e). In both cases, the ligand coordinates to both the N and S atoms.…”

Section: Chemical Contextmentioning

confidence: 99%

The crystal structures, Hirshfeld surface analyses and energy frameworks of two hexathiapyrazinophane regioisomers; 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane and 2,5,8,11,14,17-hexathia-[9.9](2,5,3,6)-pyrazinophane

Assoumatine

Stœckli-Evans

2020

Acta Cryst E

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The title thiapyrazinophanes, 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane, C16H24N2S6, (I), and 2,5,8,11,14,17-hexathia-[9.9](2,5,3,6)-pyrazinophane, C16H24N2S6, (II), are regioisomers; m-bis L1 and p-bis L1, respectively. Both compounds have a central tetra-2,3,5,6-methylenepyrazine unit with two –S—CH2—CH2—S—CH2—CH2—S– chains, linking the methylene C atoms at positions 2 and 6 and 3 and 5 on the pyrazine ring of I, but linking the methylene C atoms at positions 2 and 5 and 3 and 6 on the pyrazine ring of II. Both compounds crystallize with half a molecule in the asymmetric unit. The whole molecule of I is generated by inversion symmetry, with the pyrazine ring being located about a center of symmetry. The whole molecule of II is generated by twofold rotation symmetry, with the pyrazine N atoms being located on the twofold rotation axis. In compound I, there are pairs of intramolecular C—H...S contacts present, but none in compound II. In the crystal of I, there are no significant intermolecular interactions present, while in the crystal of II, molecules are linked by pairs of C—H...S hydrogen bonds, forming corrugated layers lying parallel the ac plane. The Hirshfeld surfaces and the energy frameworks of the two regioisomers indicate little difference in the interatomic contacts, which are dominated by dispersion forces.

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“…The synthesis and crystal structure of the ligand 2,5,8,11,14,17hexathia-[9.9](2,6,3,5)-pyrazinophane (L1), have been reported (Assoumatine & Stoeckli-Evans, 2020a).…”

Section: Synthesis and Crystallizationmentioning

confidence: 99%

Crystal structures of [(μ₂-L1)dibromidodicopper(II)] dibromide and poly[[(μ₂-L1)diiodidodicopper(I)]-di-μ-iodido-dicopper(I)], where L1 is 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane

Assoumatine

Stœckli-Evans

2020

Acta Cryst E

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The reaction of the hexathiapyrazinophane ligand, 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane (L1), with copper(II) dibromide led to the formation of a binuclear complex, [μ2-2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane]bis[bromidocopper(II)] dibromide, [Cu2Br2(C16H24N2S6)]Br2, (I). The complex possesses inversion symmetry with the pyrazine ring being situated about a center of symmetry. The ligand coordinates to the copper(II) atom in a bis-tetradentate manner and the copper atom has a fivefold NS3Br coordination environment with a distorted shape. The reaction of ligand L1 with copper(I) iodide also gave a binuclear complex, which is bridged by a Cu2I2 unit to form a two-dimensional coordination polymer, poly[[μ2-2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane]tetra-μ-iodido-tetracopper(I)], [Cu4I4(C16H24N2S6)] n , (II). The binuclear unit possesses inversion symmetry with the pyrazine ring being located about a center of symmetry. The Cu2I2 unit is also located about an inversion center. The two independent copper(I) atoms are both fourfold coordinate. That coordinating to the ligand L1 in a bis-tridentate manner has an NS2I coordination environment and an irregular shape, while the second copper(I) atom, where L1 coordinates in a bis-monodentate manner, has an SI3 coordination environment with an almost perfect tetrahedral geometry. In the crystal of I, the cations and Br− anions are linked by a number of C—H...S and C—H...Br hydrogen bonds, forming a supramolecular network. In the crystal of II, the two-dimensional coordination polymers lie parallel to the ab plane and there are no significant inter-layer contacts present.

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trans-Bis(acetonitrile-N)tetraaquanickel(II) dibromide

Cited by 7 publications

References 1 publication

Transition Metal-Based Dimeric Metallosurfactants: From Organic–Inorganic Hybrid Structures and Low-Dimensional Magnets to Metallomicelles

Transition Metal-Based Dimeric Metallosurfactants: From Organic–Inorganic Hybrid Structures and Low-Dimensional Magnets to Metallomicelles

The crystal structures, Hirshfeld surface analyses and energy frameworks of two hexathiapyrazinophane regioisomers; 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane and 2,5,8,11,14,17-hexathia-[9.9](2,5,3,6)-pyrazinophane

Crystal structures of [(μ₂-L1)dibromidodicopper(II)] dibromide and poly[[(μ₂-L1)diiodidodicopper(I)]-di-μ-iodido-dicopper(I)], where L1 is 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane

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trans-Bis(acetonitrile-N)tetraaquanickel(II) dibromide

Cited by 7 publications

References 1 publication

Transition Metal-Based Dimeric Metallosurfactants: From Organic–Inorganic Hybrid Structures and Low-Dimensional Magnets to Metallomicelles

Transition Metal-Based Dimeric Metallosurfactants: From Organic–Inorganic Hybrid Structures and Low-Dimensional Magnets to Metallomicelles

The crystal structures, Hirshfeld surface analyses and energy frameworks of two hexathiapyrazinophane regioisomers; 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane and 2,5,8,11,14,17-hexathia-[9.9](2,5,3,6)-pyrazinophane

Crystal structures of [(μ2-L1)dibromidodicopper(II)] dibromide and poly[[(μ2-L1)diiodidodicopper(I)]-di-μ-iodido-dicopper(I)], where L1 is 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane

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Crystal structures of [(μ₂-L1)dibromidodicopper(II)] dibromide and poly[[(μ₂-L1)diiodidodicopper(I)]-di-μ-iodido-dicopper(I)], where L1 is 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane