(<i>Z</i>)-2,3-Dichloro-1,1,4,4-tetrakis(4-chlorophenyl)but-2-ene

The electrolytic reductive dechlorination of 1,1-bis(p-chlorophenyl)-2,2,2-trichloroethane (DDT) in the ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF(4)]) in the presence of a cobalamin derivative afforded 1,1'-(ethylidene)bis(4-chlorobenzene)(DDO) and 1,1'-(ethenylidene)bis(4-chlorobenzene)(DDNU) with 1,1'-(2-chloroethylidene)bis(4-chlorobenzene)(DDMS); the enhanced reactivity, as well as the recyclability of the cobalamin derivative catalyst in IL, makes the present system more efficient for the development of "green" technologies.

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Enhanced reactivity of hydrophobic vitamin B12 towards the dechlorination of DDT in ionic liquid

Jabbar

Shimakoshi

Hisaeda

2007

Chem. Commun.

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(Z)-2,3-Dichloro-1,1,4,4-tetrakis(4-chlorophenyl)but-2-ene

Abstract: The title compound, C28H18Cl6, was obtained by the electrolysis of 2,2,2‐trichloro‐1,1‐bis(4‐chlorophenyl)ethane (DDT) in the presence of a catalytic amount of the cobalamin derivative heptamethyl cobyrinate perchlorate. The alkene group of the molecule has a Z configuration.

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Enhanced reactivity of hydrophobic vitamin B12 towards the dechlorination of DDT in ionic liquid

Enhanced reactivity of hydrophobic vitamin B12 towards the dechlorination of DDT in ionic liquid

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