2011
DOI: 10.1107/s1600536811017296
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(Z)-4-(2,5-Di-tert-butylanilino)pent-3-en-2-one

Abstract: In the crystal structure of the title ketoamine, C19H29NO, the bond lengths from the N atom through the alkene group to the ketone O atom show the presence of an extensively delocalized π-system. The dihedral angle between the plane of the phenyl ring and that of the alkene component is 63.45 (7)° due to steric hindrance exerted by the tert-butyl groups. The mol­ecule has a Z-configured alkene function, which is facilitated by an intra­molecular N—H⋯O hydrogen bond between the amine and ketone groups. The mol­… Show more

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