θ-[Mo₈O₂₆]⁴⁻-based multifunctional hybrid material for high catalytic performance on the cycloaddition of CO₂, esterification and knoevenagel condensation

Abstract

To develop materials with excellent properties has become the norm in the field of basic research, which prompt us to explore highly robust hybrid materials based on electron-rich POMs and...

Four octamolybdate compounds with properties of organic dye adsorption and photocatalytic reduction of Cr(vi)

“…It is advantageous to control the structure and characteristics of POM-based metal–organic complexes (MOCs) by using rationally designed organic ligands. 17,18 Organoamine has been used to create a variety of intriguing structures, including imidazole, triazole, tetrazole, pyrazole, and others. Triazole derivatives have been used frequently to create inventive POM-based MOCs.…”

Catalytic comparison of cyanosilylation/Knoevenagel condensation reactions by Pb-based heterometallic organic frameworks with different second metal ions

“…At present, the catalysts reported for cyanosilylation and Knoevenagel condensation reactions are mainly homogeneous catalytic systems consisting of Lewis acid–base sites. 36–38 For this purpose, the HMOFs 1–4 designed in this work are able to provide more catalytic active sites for enhanced catalytic performance, as will be discussed in detail later. Compared with the monometallic MOF, 1–4 may exhibit excellent catalytic properties.…”