I2O in solution and volatility

Furrow, Stanley D.; Schmitz, Guy

doi:10.1016/j.cplett.2019.05.052

Cited by 3 publications

(1 citation statement)

References 29 publications

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“…The difficulty of studying these mechanisms is increased by the fact that some intermediates have only been recently detected (for example, before mentioned I 2 O). 45 One can assume that the mechanisms of the redox reactions are particularly complex. On the other hand, it has been lately reported that the oxidation reactions between organic compounds and free radical intermediates occur via hydrogen atom transfer (HAT) mechanism.…”

Section: Figurementioning

confidence: 99%

Insight into the Origin of Pyrocatechol Inhibition on Oscillating Bray-Liebhafsky Reaction: Combined Experimental and Theoretical Study

Maksimović

Tošović

Pagnacco

2020

Bulletin of the Chemical Society of Japan

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Advance Publication is a service for online publication of manuscripts prior to releasing fully edited, printed versions. Entire manuscripts and a portion of the graphical abstract can be released on the web as soon as the submission is accepted. Note that the Chemical Society of Japan bears no responsibility for issues resulting from the use of information taken from unedited, Advance Publication manuscripts.

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Section: Figurementioning

confidence: 99%

Insight into the Origin of Pyrocatechol Inhibition on Oscillating Bray-Liebhafsky Reaction: Combined Experimental and Theoretical Study

Maksimović

Tošović

Pagnacco

2020

Bulletin of the Chemical Society of Japan

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Influence of L-tyrosine on dynamics of Bray-Liebhafsky oscillatory reaction in batch reactor. Experimental investigation and numerical modeling

Maksimović,

Ivanović-Šašić,

Maćešić

et al. 2024

Journal of Molecular Structure

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The Bray–Liebhafsky Oscillatory Reaction as a Chemosensor for Benzenediols

Pavićević,

Veles,

Maksimović

et al. 2024

Chemosensors

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Benezediols are widely used in different areas of industry, thus identification and quantification of benzenediols is of utmost importance due to their toxicity and high environmental abundance. In this work, benzenediol isomers (pyrocatechol, resorcinol, and hydroquinone) were investigated by using the Bray–Liebhafsky (BL) oscillatory reaction. All three isomers exhibit different behavior in the BL reaction, which renders the BL system applicable as a chemosensor. The period between the fifth and sixth oscillation, the amplitude of the sixth oscillation and in the case of hydroquinone, the emergence of a new oscillation in the BL reaction were selected as the parameters used for the identification and quantification of these isomers. Furthermore, electron paramagnetic resonance spectroscopy and DFT calculations were performed in order to provide insights into the mechanism of benzenediols reactions with the BL system.

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I2O in solution and volatility

Cited by 3 publications

References 29 publications

Insight into the Origin of Pyrocatechol Inhibition on Oscillating Bray-Liebhafsky Reaction: Combined Experimental and Theoretical Study

Insight into the Origin of Pyrocatechol Inhibition on Oscillating Bray-Liebhafsky Reaction: Combined Experimental and Theoretical Study

Influence of L-tyrosine on dynamics of Bray-Liebhafsky oscillatory reaction in batch reactor. Experimental investigation and numerical modeling

The Bray–Liebhafsky Oscillatory Reaction as a Chemosensor for Benzenediols

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