In view of the lack of ready formulae for modification calculation of non-standard planetary spur gear trains, the paper is focused on new modification methods of non-standard planetary spur gear trains with X-gears. Firstly, a novelty transform method from the parameters on the pitch circle to the parameters on the reference circle for a non-standard planetary spur gear train with X-gears is proposed in order to study the modification method. Secondly, a scheme of teeth surface modification for non-standard planetary spur gear train with X-gears is put forward. Thirdly, the calculation method of loaded transmission error and flash temperature on the tooth surface under mixed elastohydrodynamic lubrication for external meshing spur gear pairs is proposed using tooth contact analysis as well as loaded tooth contact analysis. Then, a new modification optimization method for non-standard planetary spur gear train with X-gears is proposed, and formulae of the maximal modification length along the tooth height are derived. Finally, the effectiveness of the modification optimization method is confirmed by an example, and the transform formulae of the optimized modification parameters for sun gear are derived.