This paper is devoted to studying the following fractional L 2 -critical nonlinear Schrödinger equation≥ 0 is an external potential. We obtain normalized L 2 -norm solutions of the above equation by solving the associated constraint minimization problem (1.4). It shows that there is a threshold a * > 0 such that (1.4) has minimizers for 0 < a < a * , and minimizers do not exist for any a > a * . For the case of a = a * , it gives a fact that the existence and non-existence of minimizers depend strongly on the value of V (0). Especially for V (0) = 0, we prove that minimizers occur blow-up behavior and the mass of minimizers concentrates at the origin as a ր a * . Applying implicit function theorem, the uniqueness of minimizers is also proved for a > 0 small enough.