The expected growth of air traffic in the coming decades demands an increase in airspace capacity, which is already close to saturation in many scenarios. One of the limiting factors of this capacity is the separation minima. At present, the separation standards that apply in a given volume of airspace are fixed, and their values were determined decades ago. Therefore, in order to increase airspace capacity, this is an area in which improvement is sought, namely through the implementation of new operational concepts, which include the redefinition of separation minima and the way they are applied. A key issue in this redefinition of separation minima is the question of the possibility of reducing the current standards. However, a reduction in the separation to a fixed value may not be a valid solution, as not all aircraft and ways of operation are the same. In this paper, the authors propose a new operational concept, the Ad Hoc or Variable separation minima. Ad Hoc separation refers to the application of different separation minima values in the same volume of airspace, depending on a set of factors, e.g., aircraft model and encounter geometry, among others. In this research, the factors that define these Ad Hoc separation minima and their relationships are discussed. A model for their determination is presented. Simulations are performed to analyze the operational feasibility of the Ad Hoc separation minima. The results show that the application of this concept is operationally feasible.