In this paper we propose an identification method of nonlinear system. This later can be structured by Wiener models. The determination of nonlinear system parameters can be done using spectral analysis. The system nonlinearity is allowed to be noninvertible general shape nonlinearity but it must be approximated by a polynomial function. The polynomial degree n can vary from one interval to another. The linear dynamic element is not-necessarily parametric but BIBO stable. In this work, a spectral method is developed allowing the estimates of the complex frequency gain as well as the estimates of nonlinear block parameters the identification method is built using one stage.