Coal seam D belongs to Muara Enim Formation in Central Palembang Subbasin, South Sumatera Basin, which ages of Middle Miocene to Late Miocene. This study aims to determine the quality of the coal, especially sulphur content and form, ash content and composition, and trace elements of heavy metals. Those are important to know as a reference in suitability in the use of this coal. Methods of analysis is proximate, total of sulphur, form of sulphur, SEM-EDS, ash composition, and trace element. The coal is categorized as low rank coal or lignite with a very low total sulphur max 0.25%, dominated by the organic sulphur formed during the peatification and coalification process (syngenetic). The coal has a safe ash composition. It shows from a very low metal oxide content that causes slagging and fouling at low temperatures process. Likewise, the trace element content of the coal such as chromium (Cr), cadmium (Cd), manganese (Mn), lead (Pb), nickel (Ni) is still far below the threshold for trace element content in coal.