“…To meet the food demand of the escalating global population and ensure the sustained growth of crop yields, pesticides (fungicide, insecticide, herbicide, etc.) and fertilizers have been intensively used and made outstanding contributions over the past century. − Nevertheless, agricultural productivity is continuously challenged by various biotic and abiotic stresses, such as phytopathogen, pest, weed, and nutrient deficiency, leading to the increasing use of agrochemicals. − Moreover, based on the traditional farming methods to administer agrochemicals, many agrochemicals fail to reach the targets but are lost by volatilization, soil leaching, photolysis, and degradation, resulting in a series of adverse effects on the ecological environment and human health, − such as soil degradation, , pesticides resistance, − and water pollution. − Therefore, reducing the application amount of agrochemicals while increasing their effectiveness is highly desired. − Fortunately, introducing advanced materials into the agricultural system provides new technical support for realizing the controlled and targeted delivery of agrochemicals and fulfilling the requirements of high yield, high quality, and sustainable development of modern agriculture. − Over the past few decades, researchers have been committed to designing and constructing advanced nanoplatforms with superior performance to deliver agrochemicals to specific target sites and release them on demand without losing effectiveness. − However, some inorganic/organic nanoplatforms including polymer micelles, carbon-based nanomaterials, metal/metal oxide nanomaterials, lipid nanoparticles, and dendrimers suffer from severe drawbacks of poor biosafety and biodegradability, low cargo loading capacity, complicated synthesis conditions, and high cost, which severely limits their applications in crop protection and growth promotion. , …”