“…A surrogate fuel is defined as a fuel with only a few representative components to mimic certain characteristics of complex fuels, such as gasoline, diesel, and jet fuel, which usually contain n -alkanes, branched alkanes, cycloalkanes, aromatics, and others. , For low-molecular-weight fuels, such as gasoline, there are a lot of simple branched alkanes, such as iso -octane, iso -pentane, , –methylhexane, , –methylbutane, , –and dimethylhexane, , that can be considered as surrogate candidate components. However, high-molecular-weight fuels, such as diesel, jet fuel, bio-derived hydroprocessed renewable jet fuel, and hydroprocessed renewable diesel fuels, usually contain a high quantity of iso-paraffinic molecular structures with an average number of carbon atom more than 15. However, until now, only iso -cetane (C 16 H 34 , 2,2,4,4,6,8,8-heptamethylnonane) − has been selected to represent the branched alkanes class because of the lack of reliable kinetic models for other highly branched alkanes with more carbon atoms.…”