2011
DOI: 10.1111/j.1747-1567.2010.00660.x
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Ignition Energy of Deposit Sulfur Powder

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“…[ 53 , 54 ] Besides, the introduction of a sulfur atom in carboranes may be conducive to ignition performance. [ 55 , 56 ] Based on the above considerations, we initially synthesized a carboranylthiolate‐protected superatomic copper‐cluster, Cu 14 (BC‐S) 6 (CH 3 CN) 8 (BC‐S = 1,2‐dithiolate‐ o ‐carborane, abbreviated as Cu 14C‐S ), in which the dithiolate units attaching to the carbon atoms of carborane clusters. Upon contact with “rocket grade” HTP oxidizer, Cu 14C‐S demonstrates hypergolicty but an ultralong ID time of 6870 ms (Figure 1 ).…”
Section: Introductionmentioning
confidence: 99%
“…[ 53 , 54 ] Besides, the introduction of a sulfur atom in carboranes may be conducive to ignition performance. [ 55 , 56 ] Based on the above considerations, we initially synthesized a carboranylthiolate‐protected superatomic copper‐cluster, Cu 14 (BC‐S) 6 (CH 3 CN) 8 (BC‐S = 1,2‐dithiolate‐ o ‐carborane, abbreviated as Cu 14C‐S ), in which the dithiolate units attaching to the carbon atoms of carborane clusters. Upon contact with “rocket grade” HTP oxidizer, Cu 14C‐S demonstrates hypergolicty but an ultralong ID time of 6870 ms (Figure 1 ).…”
Section: Introductionmentioning
confidence: 99%