A dual-particle imager based on a rotational modulation collimator (RMC) utilizing a Cs2LiYCl6:Ce (CLYC) scintillator was developed and investigated for its dual-particle imaging performance. Design considerations and previous simulation work were verified by conducting experiments, and experimental results showing neutron and gamma-ray imaging capabilities were obtained. The imaging performance of the CLYC-based RMC system was further evaluated by investigating it in a mixed neutron and gamma-ray environment, and dualparticle imaging capability of the RMC system was demonstrated. Signal-to-noise ratio values larger than 45 were achieved for reconstructed images of each neutron and gamma-ray source distribution, if modulation patterns were obtained with average fractional counting uncertainty of less than 3%. The structural similarity index of reconstructed images was calculated to be almost unity, indicating an artifact-free image.