2011
DOI: 10.1134/s1070428011090168
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Imidazo[1,2-a]benzimidazole derivatives: XXIX. 1-allyl-2-amino-3-acylmethylbenzimidazolium halides and syntheses on their base

Abstract: Cyclization of 1-allyl-2-amino-3-acylmethylbenzimidazolium halides under alkaline conditions gave 9-allyl-substituted imidazo[1,2-a]benzimidazoles. Cyclization of the same compounds on heating in concentrated hydrobromic acid was accompanied by addition of hydrogen bromide at the exocyclic double bond.

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“…[23][24][25] Analogous compounds were also synthesised by cyclisation of a chlorobenzimidazole intermediate prepared with the use of phosphoryl chloride. The method was based on the intramolecular cyclisation of appropriate 2-(chloroalkylamino)benzimidazoles 21.…”
Section: Halogens As Functional Group Xmentioning
confidence: 99%
“…[23][24][25] Analogous compounds were also synthesised by cyclisation of a chlorobenzimidazole intermediate prepared with the use of phosphoryl chloride. The method was based on the intramolecular cyclisation of appropriate 2-(chloroalkylamino)benzimidazoles 21.…”
Section: Halogens As Functional Group Xmentioning
confidence: 99%