Imidazolium based ionic liquids modified polysaccharides for adsorption and solid-phase extraction applications: A review

Saheed, Ismaila Olalekan; Azeez, Samsudeen Olanrewaju; Suah, Faiz Bukhari Mohd

doi:10.1016/j.carbpol.2022.120138

Cited by 23 publications

(5 citation statements)

References 107 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Polysaccharides are a good choice as a support for grafting different types of ILs due to their nontoxicity, compatibility with the environment, and availability. − Cellulose is a widespread polysaccharide, which is a highly fascinating material because of its renewability, high availability, low price, and suitable mechanical properties. , This natural polymer as well as nanosilica and other inorganic supports containing hydroxyl groups is used as an economic and green support for various surface chemistry applications. − The hydroxyl groups on the cellulose surface can be modified with different kinds of organic compounds. , The modified cellulose as novel surface-active compounds was introduced as efficient and green chemical materials to demulsify different kinds of W/O emulsions. − In 2020, Gómez-Jaimes et al reported the amidated cellulose nanofibrils as an effective demulsifier for W/O emulsion breaking . They synthesized the nanocellulose-based materials, TOCN-AMDC12 and TOCN-AMDC18, employed for breaking of the W/O emulsion with good DEs.…”

Section: Introductionmentioning

confidence: 99%

Demulsification of Crude Oil Emulsions Using Versatile and Eco-Friendly Demulsifiers Based on Cellulose Decorated with Imidazolium-Bearing Triazole Moiety

2023

View full text Add to dashboard Cite

Water in the crude oil forms emulsions that must be broken before refining processes. Here, the novel and versatile derivatives of imidazolium ionic liquids (ILs) containing triazole moiety [SIm-TazCn][Br] were synthesized via click chemistry and then grafted onto the cellulose (CEL) to prepare eco-friendly demulsifiers for breaking water-in-oil (W/O) emulsions. The prepared compounds with two kinds of alkyl chains named CEL[SIm-TazC6][Br] and CEL[SIm-TazC10][Br] were characterized and employed for demulsifying W/O (30:70 and 50:50 vol %) emulsions. Also, the effect of the type and concentration of each demulsifier on the phase separation and dehydration efficiency (DE) were investigated through the bottle test. According to the bottle test results, the CEL[SIm-TazC6][Br] derivative at 4000 ppm showed a good DE of 79% after 5 min, which increased to 82% after 24 h. The interfacial tension (IFT) of derivatives at different concentrations was measured. The minimum IFT value of 16.3 mN/m was obtained for CEL[SIm-TazC6][Br] with a shorter alkyl chain at 4000 ppm after 24 h. The green and efficient CEL-based surfactants significantly demulsified the W/O emulsions because of the collaboration between imidazolium and triazole moieties.

show abstract

Section: Introductionmentioning

confidence: 99%

Demulsification of Crude Oil Emulsions Using Versatile and Eco-Friendly Demulsifiers Based on Cellulose Decorated with Imidazolium-Bearing Triazole Moiety

2023

View full text Add to dashboard Cite

show abstract

“…), agriculture wastes and so on. [12][13][14][15] The most widely used cyclodextrin product produced in large quantities in industry is b-cyclodextrin. b-Cyclodextrin (b-CD), containing 7 glucose units, has a hydrophobic cavity inside and a great number of hydroxyl groups on the outside.…”

Section: Introductionmentioning

confidence: 99%

Polyethyleneimine-functionalized β-cyclodextrin porous polymers for enhanced elimination of U(vi) from wastewater

Zhong,

Lv,

Yang

et al. 2023

New J. Chem.

View full text Add to dashboard Cite

show abstract

“…Many studies have shown that PILs interact with adsorbates , (anionic dyes, metal oxoacid ions, and anion metal complexes) by ion exchanging, H-bonding, π-type interactions, and so on, showing promising application prospects in the separation and purification field. Imidazolium-based PILs have showed an unprecedentedly high sorption capacity for Cr(VI) and methyl orange (MO) .…”

Section: Introductionmentioning

confidence: 99%

Selective and Efficient Platinum Group Metal Adsorption from Wastewater by Localized Triethylamine-Based Poly(Ionic Liquid)

Zhang,

Huang

et al. 2023

ACS EST Water

View full text Add to dashboard Cite

With environmental problems and resource scarcity, it is urgent to recover Platinum Group Metals (PGMs) from wastewater. In this study, poly(styrene-triethylammonium cation) (PIL-TEA) was synthesized, characterized, and used as adsorbent for Pt(II), Pt(IV), and Ir(IV) in both synthetic and real wastewater. Various isotherm and kinetic models were employed to analyze the adsorption process, revealing that it involves chemisorption, with internal diffusion being the crucial step. The different adsorption performances of PGMs can be attributed to factors such as electrostatic interaction, weak bonding, configuration, and electrostatic potential (ESP) between anions and cations. Notably, ESP complementarity dictates the actual adsorption performance order: Pt(II) > Pt(IV) > Ir(IV). The higher the degree of ESP complementarity, the stronger the adsorption tendency. Furthermore, the study reveals that localized triethylammonium exhibits remarkable adsorption efficiency for trace PGMs in wastewater, with adsorption capacities reaching 1.615, 1.354, and 1.010 mmol/g for Pt(II), Pt(IV), and Ir(IV) respectively. Overall, this research demonstrates the excellent adsorption performance of PIL-TEA for recovering PGMs from wastewater thanks to its exceptional ability to resist miscellaneous ion interference. It also provides valuable insights into the relationship between the adsorption performance and the structure− property interplay in wastewater.

show abstract

Imidazolium based ionic liquids modified polysaccharides for adsorption and solid-phase extraction applications: A review

Cited by 23 publications

References 107 publications

Demulsification of Crude Oil Emulsions Using Versatile and Eco-Friendly Demulsifiers Based on Cellulose Decorated with Imidazolium-Bearing Triazole Moiety

Demulsification of Crude Oil Emulsions Using Versatile and Eco-Friendly Demulsifiers Based on Cellulose Decorated with Imidazolium-Bearing Triazole Moiety

Polyethyleneimine-functionalized β-cyclodextrin porous polymers for enhanced elimination of U(vi) from wastewater

Selective and Efficient Platinum Group Metal Adsorption from Wastewater by Localized Triethylamine-Based Poly(Ionic Liquid)

Contact Info

Product

Resources

About