Imine-functionalized organotin(IV) carboxylates: Syntheses, structures and antibacterial activities

Vinayak, Richa; Basu, Debayan; Bhowmick, Arghya; Ghosh, Abhrajyoti; Pada Nayek, Hari

doi:10.1016/j.ica.2024.122093

Inorganica Chimica Acta

2024

DOI: 10.1016/j.ica.2024.122093

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Imine-functionalized organotin(IV) carboxylates: Syntheses, structures and antibacterial activities

Richa Vinayak,

Debayan Basu,

Arghya Bhowmick

et al.

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2025

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Cited by 2 publications

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Syntheses, crystal structures, and anticancer activities of organotin carboxylates based on Alrestatin

Tan,

Zhang,

Liu

et al. 2025

Journal of Molecular Structure

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Syntheses, crystal structures, and anticancer activities of organotin carboxylates based on Alrestatin

Tan,

Zhang,

Liu

et al. 2025

Journal of Molecular Structure

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Organotin(IV) Compounds as Catalysts for the Solvent-Free Synthesis of Naphthofurans

Kumar,

Nayek

2024

Organometallics

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Four distinct organotin(IV) compounds, [R 2 Sn-(L 1 )] [R = Ph (1) and n-Bu (2)] and [R 2 Sn(L 2 )] [R = Ph (3) and n-Bu (4)], have been synthesized from two polydentate proligands such as 2-((2-hydroxy-3-methoxybenzylidene)amino)-4-methyl phenol (H 2 L 1 ) and 4-(tert-butyl)-2-(((2-hydroxy-5-methylphenyl)imino)methyl)phenol (H 2 L 2 ). The organotin(IV) compounds were synthesized by the reaction of organotin(IV) halides such as Ph 2 SnCl 2 and (n-Bu) 2 SnCl 2 with both proligands using Et 3 N as a base. All compounds were fully characterized using FT-IR spectroscopy; 1 H, 13 C{ 1 H}, and 119 Sn NMR spectroscopy; HRMS spectrometry; and single-crystal X-ray diffraction analysis. The Lewis acidity of all compounds was determined by the Gutmann− Beckett method. The catalytic activities of all of the compounds were investigated for the synthesis of naphthofurans from trans-β-nitrostyrene derivatives and β-naphthol or α-naphthol under solvent-free conditions. The maximum yield of naphthofurans is up to 95%.

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Imine-functionalized organotin(IV) carboxylates: Syntheses, structures and antibacterial activities

Cited by 2 publications

References 59 publications

Syntheses, crystal structures, and anticancer activities of organotin carboxylates based on Alrestatin

Syntheses, crystal structures, and anticancer activities of organotin carboxylates based on Alrestatin

Organotin(IV) Compounds as Catalysts for the Solvent-Free Synthesis of Naphthofurans

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