This paper proposes a new composite noncertainty-equivalence adaptive (CNCEA) control system for the attitude (roll, pitch, and yaw angle) control of a spacecraft in an orbit around a uniformly rotating asteroid based on the immersion and invariance (I&I) theory. For the design, it is assumed that the asteroid's gravitational parameters and the spacecraft's inertia matrix are not known. In contrast to certainty-equivalence adaptive (CEA) or noncertainty-equivalence adaptive (NCEA) systems, the CNCEA attitude control system's composite identifier uses the attitude angle tracking error, a nonlinear state-dependent vector function, and model prediction error for parameter estimation. The Lyapunov analysis shows that in the closed-loop system, the Euler angles asymptotically track the reference attitude trajectories. Interestingly, there exist two parameter error-dependent attractive manifolds, to which the closed-loop system's trajectories converge. Moreover, the composite identifier using two types of error signals provides stronger stability properties in the closed-loop system. Simulation results are presented for the attitude control of a spacecraft orbiting in the vicinity of the asteroid 433 Eros. These results show precise nadir pointing attitude regulation, despite uncertainties in the system.