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Realistic immiscible viscous fingering, showing all of the complex finger structure observed in experiments, has proven to be very difficult to model using direct numerical simulation based on the two-phase flow equations in porous media. Recently, a method was proposed by the authors to solve the viscous-dominated immiscible fingering problem numerically. This method gave realistic complex immiscible fingering patterns and showed very good agreement with a set of viscous unstable 2D water → oil displacement experiments. In addition, the method also gave a very good prediction of the response of the system to tertiary polymer injection. In this paper, we extend our previous work by considering the effect of wettability/capillarity on immiscible viscous fingering, e.g. in a water → oil displacements where viscosity ratio $$\left( {\mu_{{\text{o}}} /\mu_{{\text{w}}} } \right) \gg 1$$ μ o / μ w ≫ 1 . We identify particular wetting states with the form of the corresponding capillary pressure used to simulate that system. It has long been known that the broad effect of capillarity is to act like a nonlinear diffusion term in the two-phase flow equations, denoted here as $$D(S_{w} )$$ D ( S w ) . Therefore, the addition of capillary pressure, $$P_{c} (S_{w} )$$ P c ( S w ) , into the equations acts as a damping or stabilisation term on viscous fingering, where it is the derivative of this quantity that is important, i.e. $$D(S_{w} )\sim\left( {dP_{c} (S_{w} )/dS_{w} } \right)$$ D ( S w ) ∼ d P c ( S w ) / d S w . If this capillary effect is sufficiently large, then we expect that the viscous fingering to be completely damped, and linear stability theory has supported this view. However, no convincing numerical simulations have been presented showing this effect clearly for systems of different wettability, due to the problem of simulating realistic immiscible fingering in the first place (i.e. for the viscous-dominated case where $$P_{c} = 0$$ P c = 0 ). Since we already have a good method for numerically generating complex realistic immiscible fingering for the $$P_{c} = 0$$ P c = 0 case, we are able for the first time to present a study examining both the viscous-dominated limit and the gradual change in the viscous/capillary force balance. This force balance also depends on the physical size of the system as well as on the length scale of the capillary damping. To address these issues, scaling theory is applied, using the classical approach of Rapport (1955), to study this scaling in a systematic manner. In this paper, we show that the effect of wettability/capillarity on immiscible viscous fingering is somewhat more complex and interesting than the (broadly correct) qualitative description above. From a “lab-scale” base case 2D water → oil displacement showing clear immiscible viscous fingering which we have already matched very well using our numerical method, we examine the effects of introducing either a water wet (WW) or an oil wet (OW) capillary pressure, of different “magnitudes”. The characteristics of these two cases (WW and OW) are important in how the value of corresponding $$D(S_{w} )$$ D ( S w ) functions, relate to the (Buckley–Leverett) shock front saturation, $$S_{wf}$$ S wf , of the viscous-dominated ($$P_{c} = 0$$ P c = 0 ) case. By analysing this, and carrying out some confirming calculations, we show clearly why we expect to see much clearer immiscible fingering at the lab scale in oil wet rather than in water wet systems. Indeed, we demonstrate why it is very difficult to see immiscible fingering in WW lab systems. From this finding, one might conclude that since no fingering is observed for the WW lab-scale case, then none would be expected at the larger “field” scale. However, by invoking scaling theory—specifically the viscous/capillary scaling group, $$C_{{{\text{VC1}}}}$$ C VC1 , (and a corresponding “shape group”, $$C_{{{\text{S}}1}}$$ C S 1 ), we demonstrate very clearly that, although the WW viscous fingers do not usually appear at the lab scale, they emerge very distinctly as we “inflate” the system in size in a systematic manner. In contrast, we demonstrate exactly why it is much more likely to observe viscous fingering for the OW (or weakly wetting) case at the lab scale. Finally, to confirm our analysis of the WW and OW immiscible fingering conclusions at the lab scale, we present two experiments in a lab-scale bead pack where $$\left( {\mu_{{\text{o}}} /\mu_{{\text{w}}} } \right) = 100$$ μ o / μ w = 100 ; no fingering is seen in the WW case, whereas clear developed immiscible fingering is observed in the OW case.
Realistic immiscible viscous fingering, showing all of the complex finger structure observed in experiments, has proven to be very difficult to model using direct numerical simulation based on the two-phase flow equations in porous media. Recently, a method was proposed by the authors to solve the viscous-dominated immiscible fingering problem numerically. This method gave realistic complex immiscible fingering patterns and showed very good agreement with a set of viscous unstable 2D water → oil displacement experiments. In addition, the method also gave a very good prediction of the response of the system to tertiary polymer injection. In this paper, we extend our previous work by considering the effect of wettability/capillarity on immiscible viscous fingering, e.g. in a water → oil displacements where viscosity ratio $$\left( {\mu_{{\text{o}}} /\mu_{{\text{w}}} } \right) \gg 1$$ μ o / μ w ≫ 1 . We identify particular wetting states with the form of the corresponding capillary pressure used to simulate that system. It has long been known that the broad effect of capillarity is to act like a nonlinear diffusion term in the two-phase flow equations, denoted here as $$D(S_{w} )$$ D ( S w ) . Therefore, the addition of capillary pressure, $$P_{c} (S_{w} )$$ P c ( S w ) , into the equations acts as a damping or stabilisation term on viscous fingering, where it is the derivative of this quantity that is important, i.e. $$D(S_{w} )\sim\left( {dP_{c} (S_{w} )/dS_{w} } \right)$$ D ( S w ) ∼ d P c ( S w ) / d S w . If this capillary effect is sufficiently large, then we expect that the viscous fingering to be completely damped, and linear stability theory has supported this view. However, no convincing numerical simulations have been presented showing this effect clearly for systems of different wettability, due to the problem of simulating realistic immiscible fingering in the first place (i.e. for the viscous-dominated case where $$P_{c} = 0$$ P c = 0 ). Since we already have a good method for numerically generating complex realistic immiscible fingering for the $$P_{c} = 0$$ P c = 0 case, we are able for the first time to present a study examining both the viscous-dominated limit and the gradual change in the viscous/capillary force balance. This force balance also depends on the physical size of the system as well as on the length scale of the capillary damping. To address these issues, scaling theory is applied, using the classical approach of Rapport (1955), to study this scaling in a systematic manner. In this paper, we show that the effect of wettability/capillarity on immiscible viscous fingering is somewhat more complex and interesting than the (broadly correct) qualitative description above. From a “lab-scale” base case 2D water → oil displacement showing clear immiscible viscous fingering which we have already matched very well using our numerical method, we examine the effects of introducing either a water wet (WW) or an oil wet (OW) capillary pressure, of different “magnitudes”. The characteristics of these two cases (WW and OW) are important in how the value of corresponding $$D(S_{w} )$$ D ( S w ) functions, relate to the (Buckley–Leverett) shock front saturation, $$S_{wf}$$ S wf , of the viscous-dominated ($$P_{c} = 0$$ P c = 0 ) case. By analysing this, and carrying out some confirming calculations, we show clearly why we expect to see much clearer immiscible fingering at the lab scale in oil wet rather than in water wet systems. Indeed, we demonstrate why it is very difficult to see immiscible fingering in WW lab systems. From this finding, one might conclude that since no fingering is observed for the WW lab-scale case, then none would be expected at the larger “field” scale. However, by invoking scaling theory—specifically the viscous/capillary scaling group, $$C_{{{\text{VC1}}}}$$ C VC1 , (and a corresponding “shape group”, $$C_{{{\text{S}}1}}$$ C S 1 ), we demonstrate very clearly that, although the WW viscous fingers do not usually appear at the lab scale, they emerge very distinctly as we “inflate” the system in size in a systematic manner. In contrast, we demonstrate exactly why it is much more likely to observe viscous fingering for the OW (or weakly wetting) case at the lab scale. Finally, to confirm our analysis of the WW and OW immiscible fingering conclusions at the lab scale, we present two experiments in a lab-scale bead pack where $$\left( {\mu_{{\text{o}}} /\mu_{{\text{w}}} } \right) = 100$$ μ o / μ w = 100 ; no fingering is seen in the WW case, whereas clear developed immiscible fingering is observed in the OW case.
Enhanced oil recovery (EOR) is critical to optimally producing existing reserves with a minimized carbon footprint. However, it is essential that the EOR process does not impact negatively on ongoing production chemistry treatments. The focus of this work is on the interactions between polymers and scale inhibitor in terms of adsorption. The adsorption of both is assessed using static adsorption tests to understand and analyze for any evidence of competitive adsorption between these species. The study also elucidates some features of the adsorption kinetics of the polymers used in this study. Copolymers of acrylamide (AM) and acrylic acid (AA) have been the most prominent chemicals to be applied in polymer EOR, whereas sulfonated polymers containing acrylamide tertiary butyl sulfonic acid (ATBS) have been used for higher temperature and/or salinity conditions. This work was carried out in a field brine at a temperature of 31°C. The polymers consisted of AA-AM co-polymers (20-33 % AA) and AM-AA-ATBS ter-polymers (up to 15 mol% ATBS) and DETPMP as a common scale inhibitor. The adsorption levels of the polymers and DETPMP were measured both separately and in sequential addition experiments (at t = t1). The adsorption results in the open laboratory were compared with anaerobic results as they may better represent the field conditions – these experiments were conducted on North Sea water at 70°C as this is a common mid-range temperature at which DETPMP would be used. While polymer adsorption levels of ~20 µg/g were measured after 24 hours, this increased continuously over 20-30 days for the AA-AM co polymers. The same trend was observed for the AM-AA-ATBS terpolymers – with adsorption at 24 hours of ~15 µg/g which again increased significantly over time. However, DETPMP adsorption when added into a pre-adsorbed layer of polymer showed a surprising behavior not reaching the equilibrium after ~ 72 hours regardless of the concentration tested, continuously increasing over time. To the author's knowledge, the DETPMP equilibrium has been reported to be around 24 hours or less. These results are amongst the first observations of this type in the literature, and they highlight the need for the industry to develop a better understanding of the competitive interactions between scale inhibitor treatments and EOR polymers.
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