2008
DOI: 10.1016/j.bioelechem.2008.07.002
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Immobilization of glucose oxidase on carbon paper electrodes modified with conducting polymer and its application to a glucose fuel cell

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Cited by 65 publications
(19 citation statements)
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“…The catalytic oxidation of glucose can be clearly seen at potentials higher than 0.12 V. The maximum current density was 1457 μA/cm 2 . This superior performance was due to the promotion of oxidation reactions by GOD and fast electron transfer by the mediator osmium complex [23,24]. The high current density saturated at a potential about 0.2 V and then showed a decrease from about 0.3 V. In this experiment, it is presumed that the reduction of the current density was due to the removal of the GOD/osmium complex mediator from the anode and the exhaustion of glucose near the surface of anode.…”
Section: Measurementsmentioning
confidence: 75%
“…The catalytic oxidation of glucose can be clearly seen at potentials higher than 0.12 V. The maximum current density was 1457 μA/cm 2 . This superior performance was due to the promotion of oxidation reactions by GOD and fast electron transfer by the mediator osmium complex [23,24]. The high current density saturated at a potential about 0.2 V and then showed a decrease from about 0.3 V. In this experiment, it is presumed that the reduction of the current density was due to the removal of the GOD/osmium complex mediator from the anode and the exhaustion of glucose near the surface of anode.…”
Section: Measurementsmentioning
confidence: 75%
“…Research findings demonstrate that enzymatic catalysts exhibit high activity and excellent selectivity, but the unstable operating environment and fragile stability greatly hinder their practical applications [5,6]. To overcome these drawbacks, non-enzymatic catalysts (such as precious metal nanoparticles or alloys [7][8][9][10], composite materials [11,12], polymers [13,14] and transition metal oxides [15][16][17][18]) as enzyme mimics show higher performance than enzymatic ones. Among these non-enzymatic catalysts, transition metal oxides play important roles due to their high intrinsic catalytic performances, low cost, and environmental friendliness.…”
Section: Introductionmentioning
confidence: 99%
“…However, the thick protein layer surrounding flavin redox centre results in difficulties on direct electron transfer between FAD and electrodes [2,3]. It has taken about half a century and tremendous amount of research to overcome this problem and to obtain better electron transfer between the enzyme and electrodes such as adding redox mediators [4], conducting polymers [5], nanoparticles [6] and dendrimers [7]. The surface quality is an important factor affecting results obtained with electrochemical methods especially when self assembled monolayers (SAMs) are applied to build a recognition layer with various functional groups.…”
Section: Introductionmentioning
confidence: 99%