Objectives:The study intends to assess the durability behaviour of Engineered Cementitious Composites containing Alccofine and fibres in mono and hybrid formats. Methods: The study comprehensively investigates ECC's response to water absorption, density, volume of permeable pores and sorptivity based on ASTM C 642 and 1585, respectively. In addition, ECC specimens were subjected to various environments such as acid, alkaline and sulphate mediums to find the performance mentioned above. Findings: The introduction of Alccofine caused a significant effect on both mechanical and durability properties. The results indicated that the inclusion of Alccofine exhibited a decrease of 18.67% of absorption and 25.89% of voids in ECC compared to the control mortar. The density of ECC increased by about 13.42%. After being exposed to acid, alkaline, and sulphate environments, the percentage loss of weight in ECC is 2.93%, 0.56%, and 0.51%, respectively, whereas in the control specimen, it was 3.92%, 0.83%and 1.51%, respectively. Percentage loss of strength also follows the same trend; the values are 14.67%, 3.27% and 11.19% in ECC, whereas in the control specimen, 23.32%, 8.33% and 16.79%, respectively. Alcconfine enhanced microstructure refinement and synthetic fibres crack mitigation behaviour improve ECC's resistance to the deterioration mechanisms. Novelty: The article reveals that adding Alccofine and hybridising fibers developed a sustainable material and found superior performance in all harsh environmental conditions. Using concrete with enhanced properties will be beneficial.