Quantum dots (QDs) allow for a significant
amount of strain relaxation,
which is helpful in GaN systems where a large lattice mismatch needs
to be accommodated. InGaN QDs with a large indium composition are
intensively investigated for light emitters requiring longer wavelengths.
These are especially important for developing high-efficiency white
light sources. Understanding the carrier dynamics in this large lattice-mismatched
system is essential to improving the radiative efficiency while circumventing
high defect density. This work investigates femtosecond carrier and
photon dynamics in self-organized In0.27Ga0.73N/GaN QDs grown by molecular beam epitaxy using transient differential
absorption spectroscopy, which measures the differential absorption
coefficient (Δα) with and without an optical pump. Due
to 3D quantum confinement and the small effective mass of InGaN, the
low density of states in the conduction band is easily filled with
electrons. In contrast, the GaN barrier region is replete with a high
density of electrons due to a large effective mass. This contrast
in carrier density creates a unique phenomenon in the dynamics, showing
a change in the differential absorption coefficient (Δα)
sign from negative to positive with time. The ultrafast microscopic
processes indicate that right after the optical pump and first photon
absorption, the valence (conduction) band states are depleted (replete)
of electrons. This ground-state bleaching process makes Δα
negative, and the probe beam is not absorbed. The electrons are then
gradually transferred from the GaN barrier into InGaN QDs, which absorb
the second photon from the probe beam (excited-state absorption),
making Δα positive. The presence of excited-state carriers
with a long lifetime is indicative of the enhanced availability of
carriers for radiative recombination. This effect also promotes stimulated
emission and amplified spontaneous emission, which can be used to
develop lasers and superluminescent LEDs, respectively. Measurements
with multiple pump powers and temperatures further confirm that the
efficacy of InGaN QDs is enhanced by this effective mass contrast
and 3D reservoir of carriers from the GaN barrier. This effect can
be used to improve the internal quantum efficiency of GaN-based light
emitters.