This study deals with the effect of electric force and magnetohydrodynamics (MHD) of the transient state on natural convection flow past an oscillating vertical plate. In addition to this, thermal radiation and porous media are also examined in the Casson fluid flow. The Poisson-Boltzmann equation is employed to show the electric potential character within the fluid region, which is put into a linear form by the implementation of Debye-Hückel linearization. It is possible to compute the precise solution to the governing equations using the Laplace transform approach. The expression of fluid velocity, fluid concentration, and temperature are exposed graphically, and numerical results for Nusselt and Sherwood numbers are also derived for vital pertinent flow constraints. Increasing electroosmosis parameters strongly boosts fluid velocity. The nonnegative values of the Helmholtz-Smoluchowski velocity highly induce the axial velocity and the negative value decelerates. With increasing radiation strength and Prandtl number, the fluid's temperature distribution diminishes. These more intricate electrokinetic rheological flows associated with electroosmotic separators, such as biomedical absorbers, are illuminated by these models.