The use of advanced fuels must increase from 0.5 to 3.6 in internal combustion engines according to the forthcoming European directive. In this frame, alcohols that can be obtained from waste or lignocellulosic materials with advanced production techniques may play an important role in the future. This work focuses on the effect of the use of butanol as a blend component on the properties of soot emmited from compression ignition engines. This knowledge is essential to decide the strategy to carry out a proper regeneration process in the Diesel Particle Filter (DPF). The study was performed in a Euro 6 diesel engine. The engine operating condition used to collect particulate matter was selected as a typical steady mode in urban driving. The blends tested were baseline diesel, Bu10D (10% butanol and 90% diesel v/v), Bu20D (20% butanol and 80% diesel v/v) and Bu10B10D (10% butanol, 10% biodiesel and 80% diesel v/v). The techniques used to characterise the soot are X-Ray Difraction (XRD), Raman spectroscopy, Transmission Electron Microscopy (TEM), surface area analyser, X-ray Photoelectron Spectroscopy (XPS), Fourier-Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). From the results shown, the average primary particle diameter, which is reduced for increasing butanol content, provided the best consistency with soot reactivity obtained from TGA and DSC.