Impact of Fluorine Atoms on Perylene Diimide Derivative for Fullerene‐Free Organic Photovoltaics

Zhao, Liang; Sun, Hua; Liu, Xiaoyuan; Liu, Chang‐Mei; Shan, Haiquan; Xia, Jiu-Xu; Xu, Zong‐Xiang; Chen, Fei; Chen, Zhi-Kuan; Huang, Wei

doi:10.1002/asia.201700661

Cited by 11 publications

(2 citation statements)

References 45 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The work successfully demonstrated that a small driving force can maximize the achievable efficiency of OSCs by reduction of V loss due to the non-radiative recombination processes, which will expand the potential possibilities of NFA-based OPV systems to lead toward a more practical technology. Although numerous examples of the bay-bridged dimeric PDIs have been explored so far [103][104][105][106][107][108][109][110][111][112][113][114][115][116][117][118][119], to the best of our knowledge, the above mentioned 3.2A/P3TEA system exhibited the highest performance due to the photovoltaic properties with the minimal voltage loss and the drastically enhanced J SC .…”

Section: Bay-bridged Dimeric Perylene Diimidesmentioning

confidence: 99%

Development of Perylene-Based Non-Fullerene Acceptors through Bay-Functionalization Strategy

et al. 2020

View full text Add to dashboard Cite

Perylene has had a tremendous impact in the history of material research for the molecular semiconductors. Among numerous derivatives of this polyaromatic hydrocarbon, perylene diimide (PDI) represents a promising class of organic materials envisioned as non-fullerene acceptors (NFAs) for the practical organic photovoltaic (OPV) applications due to their enhanced photo- and thermal stability and remarkably high electron affinity, some of which realize band-like transport properties. The present review guides some of the representative achievements in the development of rationally designed PDI systems, highlighting synthetic methodologies based on bay-functionalization strategies for creating well-designed molecular nanostructures and structure-performance relationship of perylene-based small molecular acceptors (SMAs) for the photovoltaic outcomes.

show abstract

Section: Bay-bridged Dimeric Perylene Diimidesmentioning

confidence: 99%

Development of Perylene-Based Non-Fullerene Acceptors through Bay-Functionalization Strategy

et al. 2020

View full text Add to dashboard Cite

show abstract

“…Perylenediimide derivatives are characterized by intense light absorption, high electron mobilities and good thermal stability that make these molecules suitable candidates as acceptor materials in non‐fullerene OSCs. FPDI‐CDTph and FPDI‐CDTph2F have been proven as efficient acceptors in BHJ active layers with the fluorinated polymer PTB7‐Th. Better performances have been obtained for devices with FPDI‐CDTph2F (PCE 6.03 % vs. 4.10 % of the non‐fluorinated acceptor).…”

Section: Organic Fluorinated Materials For Photovoltaicsmentioning

confidence: 99%

Organic and Organometallic Fluorinated Materials for Electronics and Optoelectronics: A Survey on Recent Research

et al. 2018

View full text Add to dashboard Cite

Conjugated organic polymers, small molecules, and transition metal organometallic complexes are used as active semiconducting materials in electronic and optoelectronic devices including organic solar cells (OSCs), organic field effect transistors (OFETS), organic light emitting diodes (OLEDs). While some of these technologies are mature and already available on the market, research is still very active in academic and industrial laboratories to gain better performances. Major drawbacks which still limit large industrial production of some of these devices are not only the non‐optimized performances, but also stability issues and cost. In fact, wide applicability of organic electronic technology largely relies on the development of efficient, durable and cost‐effective materials. Properties of molecular and polymeric semiconductors can be properly engineered and finely tuned by the design of the conjugated molecular structure and the selective introduction of various functional groups as substituents. Selective functionalization of the conjugated backbone with fluorine atoms and fluorinated substituents has been largely demonstrated to be an effective structural modification not only for tuning optoelectronic properties, but also to affect solid state organization and to improve stability. This review covers the most important classes of materials (conjugated polymers, small molecules, and organometallic complexes) reporting for each of these classes the applications in OSCs, OFETs, and OLEDs and highlighting the role of fluorine functionalization on the properties. The literature shows intriguing results that can be achieved by fluorine functionalization, and it also points out that this research field is still promising for future progress.

show abstract

Recent progress on non-fullerene acceptors for organic photovoltaics

2019

View full text Add to dashboard Cite

Impact of Fluorine Atoms on Perylene Diimide Derivative for Fullerene‐Free Organic Photovoltaics

Cited by 11 publications

References 45 publications

Development of Perylene-Based Non-Fullerene Acceptors through Bay-Functionalization Strategy

Development of Perylene-Based Non-Fullerene Acceptors through Bay-Functionalization Strategy

Organic and Organometallic Fluorinated Materials for Electronics and Optoelectronics: A Survey on Recent Research

Recent progress on non-fullerene acceptors for organic photovoltaics

Contact Info

Product

Resources

About