Dual-gate
organic thin-film transistors (DG-OTFTs) with enhanced
functionality, including large current enhancement behavior, highly
efficient threshold voltage controllability, and self-contained dual-mode
logic gate features, are reported. These DG-OTFTs are based on a semiconducting/insulating
polyblend-based active layer with asymmetric top and bottom charge
modulation layers (atb-CMLs). The atb-CMLs are automatically generated
through the preparation of multilayer stacks of phase-separated semiconducting
poly(3-hexylthiophene) (P3HT):insulating poly(methylmethacrylate)
(PMMA) polyblend layer, poly(vinylidene fluoride) (PVDF) layer, and
cross-linked-poly(4-vinylphenol) (cPVP) layer. They consist of a thin
PMMA bottom layer and an uneven-shaped PMMA:PVDF miscible mixture-based
top layer. The presence of the polarizable insulating PMMA, PVDF,
and PMMA:PVDF mixture regions causes the bottom and top CMLs to experience
electrical polarization, which induces the dipole field to achieve
efficient charge modulation functions in DG-OTFTs. Owing to the presence
of atb-CMLs, the DG-OTFTs exhibit unprecedented electrical characteristics,
such as the easy depletion of the bottom channel by the top gate potential.
However, the top channel can work properly only when given a bottom
gate potential (either positive or negative). Given these unusual
electrical features, the design of the fundamental dual-mode logic
gates (e.g., AND and OR gates) can be achieved with just one DG transistor.
This finding opens an interesting direction for the preparation of
DG-OTFTs with diverse operating modes and increasing functionality,
thereby widening the application potential of such transistors.