Impact of HCl Acidizing Treatment on Mechanical Integrity of Carbonaceous Shale

Abstract

Hydrocarbon production from unconventional resources especially shale reservoirs has tremendously increased during the past decade. Eagle Ford shale formation is one of the major sources of oil and gas in United States. However, due to extremely low permeability of this formation, stimulation treatments are implemented for hydrocarbon production. Eagle Ford shale requires a very high breakdown pressure during fracturing treatment due to high mechanical strength and low permeability. This study aims to address these challenges through applying the acidizing treatment on the shale and studying its impact. A detailed experimental investigation was carried out in this work to evaluate mechanical integrity and mineralogical and morphological changes of the shale formation when exposed to HCl acidizing treatment. Two crucial aspects of acidizing treatment, that is, impact of acid concentrations and treatment time, were given additional focus in this study. Different parameters such as porosity, nanopermeability, uniaxial compressive strength (UCS), acoustic velocities, dynamic elastic parameters, rock surface hardness (RSH) and brittleness index (BI) were analyzed before and after the acidizing treatment for different HCl concentrations. Microimaging was done through scanning electron microscopy (SEM) and whole cores were scanned using medical computed tomography (MCT) to understand the small-scale features. X-ray diffraction was used for the minerals’ identification. A continuous profile of UCS was measured through the scratch test system. Post-treatment results revealed that HCl treatment has a profound impact on rock mechanical properties of Eagle Ford shale. Considerable mass loss in core plugs was recorded after treatment at each concentration. Mineralogical composition and microimaging revealed compositional changes and porosity enhancement after the treatment. Reaction rate is higher in the first 10 min for higher acid concentrations resulting in significant changes in properties in that time interval. UCS and RSH exhibited a progressive decrease with increasing concentrations. The rate of RSH reduction increased with the increase in acid concentration nonlinearly. Acoustic velocities exhibited a considerable decrease even at low acid concentrations due to the enhancement of pore spaces. Noticeable reduction was observed in dynamic rock stiffness and BI with the increase in acid concentrations. On the contrary, Poisson’s ratio showed a significant increment. Experimental findings of this research can be used to optimize the acidizing treatment for Eagle Ford shale and other similar formations. Formation breakdown pressure can be reduced significantly by applying the acid treatment to improve the production of hydrocarbons. Furthermore, a better understanding of matrix acidizing can lead to savings in time and resources during production operations.

Mechanistic analysis of matrix-acid treatment of carbonate formations: An experimental core flooding study

“…Actually, it represents the density of the material. Higher CT number represents materials with higher density while lower CT number represents the materials with lower density [ 78 , 79 ].…”

Effect of EDTA Addition on Acidizing Treatment Process

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Study on the Degradation Effect of Carbonaceous Shale under the Coupling Effect of Chemical Erosion and High Temperature

“…Carbonaceous shale, as a typical surrounding rock in southwestern China, often appears in the tunnels along the line. The physical and mechanical properties of carbonaceous shale are affected by different degrees under the combined action of temperature and groundwater chemical erosion, which poses a great challenge to the long-term stability of tunnel engineering [4][5][6]. Therefore, the research on the deterioration effect of carbonaceous shale under chemical erosion and high temperature is of great practical significance for China to explore the laws of deep earth science and tunnel engineering design and construction in the future [7][8][9].…”