Impact of hydrogen bonding interaction energy on the polymerization kinetics of polymerizable deep eutectic solvent monomers

Abstract

The fabrication of functional materials through the polymerization of polymerizable deep eutectic solvent monomers (PDES monomers) has emerged as a novel research field in recent years. Besides, in comparison to...

Deep eutectic solvents towards green polymeric materials

“…In a recent study, Lin et al investigated the effect of a PDES (consisting of quaternary ammonium salts as the HBAs and AA as the HBD) on the polymerization kinetics of the monomer component (AA) compared to the utilization of the inert solvents DMF, DMSO, and methanol. 35 The authors reported a significantly high CC conversion (∼99%) in PDES medium as opposed to with traditional solvents (less than 30% conversion), besides the high rate of conversion. The main reason for this was attributed to the increased CC bond activity of the AA monomer (which acted as the HBD) resulting from the hydrogen bonding with the quaternary ammonium salt-based HBAs.…”

Dry ionic conductive elastomers based on polymeric deep eutectic solvents for bioelectronics

“…56,57 More recent advances by Li et al have unveiled the impact of hydrogen bonding interaction energy on the polymerization kinetics of these systems, exploring an array of quaternary ammonium salt homologs and AA. 58…”

Regioselectivity and physical nature of the interactions between (methyl)guanine with HCl and CH3OH

“…Despite having been the subject of extensive studies for more than a century, hydrogen bonding interactions are still at the heart of numerous investigations within the scientific community (1)(2)(3)(4)(5)(6)(7)(8)(9)(10). This is because they play a crucial role in various fields, from molecular recognition processes to condensed matter via the self-assembling of macromolecules (11)(12)(13)(14)(15).…”